Synthesis of Zn Aluminosilicates and Their Physicochemical and Catalytic Properties in the Aromatization of Propane | Sciact - CRIS-система Института катализа

Synthesis of Zn Aluminosilicates and Their Physicochemical and Catalytic Properties in the Aromatization of Propane Научная публикация

Журнал

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Вых. Данные

Год: 2022, Том: 96, Номер: 3, Страницы: 535-541 Страниц : 7 DOI: 10.1134/s0036024422030268

Ключевые слова

zinc aluminosilicate, crystals, clusters, aggregates, morphology, active centers, aromatization, propane

Авторы

Vosmerikova L.N. ¹ , Vosmerikov A.A. ¹ , Zaikovskii V.I. ^2,3 , Vosmerikov A.V. ¹

Организации

1	Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences, Tomsk, 634055 Russia
2	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
3	Novosibirsk State University, Novosibirsk, 630090 Russia

Информация о финансировании (1)

Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)

Zn aluminosilicates of a ZSM-5 zeolite structural type are synthesized from alkaline alumino-silica gels via hydrothermal crystallization. Structural and morphological data on the samples show that incorporating zinc into the zeolite structure leads to the formation of the particles of different morphology and elemental composition. Data from EDX analysis show that the distribution of elements throughout the zeolite catalyst is almost uniform, due to the morphology of the crystals that form. It is found that Zn aluminosilicates have high catalytic activity in the conversion of propane into aromatic hydrocarbons. A 0.81% Zn-AC sample exhibits the greatest selectivity toward aromatic compounds, due to the specific distribution and state of Zn in the zeolite and its acidic properties.

Vosmerikova L.N. , Vosmerikov A.A. , Zaikovskii V.I. , Vosmerikov A.V.
Synthesis of Zn Aluminosilicates and Their Physicochemical and Catalytic Properties in the Aromatization of Propane
Russian Journal of Physical Chemistry A. 2022. V.96. N3. P.535-541. DOI: 10.1134/s0036024422030268 WOS Scopus РИНЦ CAPlusCA OpenAlex

Восмерикова Л.Н. , Восмериков А.А. , Зайковский В.И. , Восмериков А.В.
Синтез Zn-алюмосиликатов, их физико-химические и каталитические свойства в процессе ароматизации пропана
Журнал физической химии. 2022. Т.96. №3. С.365-372. DOI: 10.31857/S0044453722030268 РИНЦ OpenAlex

Поступила в редакцию:	15 сент. 2021 г.
Принята к публикации:	21 сент. 2021 г.
Опубликована в печати:	27 мар. 2022 г.
Опубликована online:	27 мар. 2022 г.

Web of science:	WOS:000773967400010
Scopus:	2-s2.0-85127359180
РИНЦ:	48422991
Chemical Abstracts:	2022:835675
Chemical Abstracts (print):	178:209885
OpenAlex:	W4221126732

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