Catalytic Properties of M-Cu/ZrO2 (M = Fe, Co, Ni) in Steam Reforming of Ethanol | Sciact - CRIS-system of Boreskov Institute of Catalysis

Catalytic Properties of M-Cu/ZrO2 (M = Fe, Co, Ni) in Steam Reforming of Ethanol Full article

Journal

Theoretical and Experimental Chemistry
ISSN: 0040-5760 , E-ISSN: 1573-935X

Output data

Year: 2013, Volume: 48, Number: 6, Pages: 386-393 Pages count : 8 DOI: 10.1007/s11237-013-9286-x

Tags

bimetallic catalysts, cobalt, copper, ethanol, iron, nickel, steam reforming, zirconium dioxide

Authors

Deinega I.V. ¹ , Dolgykh L.Yu. ¹ , Stolyarchuk I.L. ¹ , Staraya L.A. ¹ , Strizhak P.E. ¹ , Moroz E.M. ² , Pakharukova V.P. ² , Zyuzin D.A. ²

Affiliations

1	L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv 03028, Ukraine
2	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Prospekt Akademika Lavrent’eva, 5, Novosibirsk 630090, Russian Federation

We show that bicomponent supported catalysts M-Cu/ZrO2 (M = Fe, Co, Ni) are considerably more efficient than Cu/ZrO2 in steam reforming of ethanol at 350-550 °C. We have found that Fe-Cu/ZrO2 has increased activity and selectivity in ethanol steam reforming, due to the presence of highly dispersed copper particles and iron oxide particles, which are active in the water-gas shift reaction, and as a result carbon monoxide (a secondary product of ethanol steam reforming) is converted to the target CO2 and H2.

Deinega I.V. , Dolgykh L.Y. , Stolyarchuk I.L. , Staraya L.A. , Strizhak P.E. , Moroz E.M. , Pakharukova V.P. , Zyuzin D.A.
Catalytic Properties of M-Cu/ZrO2 (M = Fe, Co, Ni) in Steam Reforming of Ethanol
Theoretical and Experimental Chemistry. 2013. V.48. N6. P.386-393. DOI: 10.1007/s11237-013-9286-x WOS Scopus РИНЦ ANCAN OpenAlex

Дейнега И.В. , Долгих Л.Ю. , Столярчук И.Л. , Старая Л.А. , Стрижак П.Е. , Мороз Э.М. , Пахарукова В.П. , Зюзин Д.А.
Каталитические свойства М-Сu/ZrO2 (M=Fe,Co,Ni) в процессе парового риформинга этанола
Теоретическая и экспериментальная химия. 2012. Т.48. №6. С.364-371. РИНЦ

Submitted:	Nov 28, 2012
Published print:	Jan 1, 2013
Published online:	Feb 27, 2013

Web of science:	WOS:000316017300006
Scopus:	2-s2.0-84880697990
Elibrary:	20445900
Chemical Abstracts:	2013:346467
Chemical Abstracts (print):	159:10759
OpenAlex:	W1976846000

DB	Citing
Web of science	10
Scopus	9
Elibrary	7
OpenAlex	6