Structure-Guided Insights into non-Catalytic (α-hydroxy)alkylation of Olefins with Alcohols Научная публикация
| Журнал |
New Journal of Chemistry
ISSN: 1144-0546 , E-ISSN: 1369-9261 |
||
|---|---|---|---|
| Вых. Данные | Год: 2022, Том: 46, Номер: 20, Страницы: 9775-9784 Страниц : 10 DOI: 10.1039/D2NJ00155A | ||
| Ключевые слова | Coagulation; Gels; Growth kinetics; Light transmission; Morphology; Optical data storage; Optical microscopy; Particle size; Polymerization; Precipitation (chemical); Size distribution | ||
| Авторы |
|
||
| Организации |
|
Информация о финансировании (1)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 0239-2021-0003 |
Реферат:
New pairs of "olefin–alcohol" were involved into the non-catalytic (α-hydroxy)alkylation process at 350 °C – the addition reaction of MeOH, EtOH or 2-PrOH to styrene, cyclohexene, 1-heptene, and limonene to produce carbon-chain elongated alcohols. The contribution of different side reactions (transfer hydrogenation, alcohol dehydration,
C-alkoxylation, etc.) was described for the first time, and the chemo- and regio-selectivity was evaluated for each pair. As a proof-of-concept, the ability of olefinic precursor to participate in two-step elimination–(α-hydroxy)alkylation tandem reaction with alcohol was confirmed: isobutylene generated in situ from tert-butanol at 350 °C reacted with MeOH to give two isomeric alcohols (isoamyl and neopentyl ones) with 34% selectivity.
Библиографическая ссылка:
Chibiryaev A.M.
Structure-Guided Insights into non-Catalytic (α-hydroxy)alkylation of Olefins with Alcohols
New Journal of Chemistry. 2022. V.46. N20. P.9775-9784. DOI: 10.1039/D2NJ00155A WOS Scopus РИНЦ CAPlusCA OpenAlex
Structure-Guided Insights into non-Catalytic (α-hydroxy)alkylation of Olefins with Alcohols
New Journal of Chemistry. 2022. V.46. N20. P.9775-9784. DOI: 10.1039/D2NJ00155A WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 11 янв. 2022 г. |
| Принята к публикации: | 14 апр. 2022 г. |
| Опубликована online: | 18 апр. 2022 г. |
| Опубликована в печати: | 24 мая 2022 г. |
Идентификаторы БД:
| Web of science: | WOS:000792323500001 |
| Scopus: | 2-s2.0-85131463203 |
| РИНЦ: | 48720658 |
| Chemical Abstracts: | 2022:1226666 |
| Chemical Abstracts (print): | 180:268101 |
| OpenAlex: | W4226051537 |