Synthesis, Luminescent and Magnetic Properties of New Tetranuclear Lanthanide Complexes with 4-hydroxy-2,1,3-benzothiadiazolate and Dibenzoylmethanide Ligands | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis, Luminescent and Magnetic Properties of New Tetranuclear Lanthanide Complexes with 4-hydroxy-2,1,3-benzothiadiazolate and Dibenzoylmethanide Ligands Full article

Journal

Polyhedron
ISSN: 0277-5387

Output data

Year: 2017, Volume: 124, Pages: 139-144 Pages count : 6 DOI: 10.1016/j.poly.2016.12.041

Tags

Benzothiadiazole; Coordination compound; Infrared luminescence; Lanthanide; Magnetic properties

Authors

Sukhikh T.S. ^1,2 , Bashirov D.A. ^1,2 , Kolybalov D.S. ² , Andreeva A.Y. ¹ , Smolentsev A.I. ¹ , Kuratieva N.V. ^1,2 , Burilov V.A. ³ , Mustafina A.R. ⁴ , Kozlova S.G. ^1,2 , Konchenko S.N. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090 Novosibirsk, Russia
2	Department of Natural Sciences, National Research University – Novosibirsk State University, 630090 Novosibirsk, Russia
3	Butlerov Institute of Chemistry, Kazan Federal University, 420008 Kazan, Russia
4	Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, 420088 Kazan, Russia

Four new tetranuclear complexes, [Ln4(dbm)4(O-btd)6(OH)2] 1a (Ln = Yb), 1b (Ln = Dy) and [Ln4(dbm)6(O-btd)4(OH)2] 2a (Ln = Yb), 2b (Ln = Dy) (O-btd = 4-hydroxo-2,1,3-benzothiadiazolate and dbm = dibenzoylmethanide), and their solvates with toluene and tetrahydrofuran were synthesized. The magnetic properties of the complexes 1a, 1b, 2a and 2b have been studied, revealing different magnetic susceptibility patterns for the Yb(III) and Dy(III) complexes in the temperature range 80–300 K. Upon lowering the temperature, a weak antiferromagnetic ordering is observed for both Yb compounds, while the Dy derivatives are assumed to show weak ferromagnetic interactions. The Yb complexes 1a and 2a demonstrate strong NIR luminescence at ∼1000 nm in CH2Cl2 solution upon excitation of the (O-btd)− ligand. This observation suggests the (O-btd)− ligand to be an efficient antenna ligand for lanthanide-based NIR luminescence.

Sukhikh T.S. , Bashirov D.A. , Kolybalov D.S. , Andreeva A.Y. , Smolentsev A.I. , Kuratieva N.V. , Burilov V.A. , Mustafina A.R. , Kozlova S.G. , Konchenko S.N.
Synthesis, Luminescent and Magnetic Properties of New Tetranuclear Lanthanide Complexes with 4-hydroxy-2,1,3-benzothiadiazolate and Dibenzoylmethanide Ligands
Polyhedron. 2017. V.124. P.139-144. DOI: 10.1016/j.poly.2016.12.041 WOS Scopus ANCAN OpenAlex

Submitted:	Oct 25, 2016
Accepted:	Dec 18, 2016
Published online:	Jan 5, 2017
Published print:	Mar 9, 2017

Web of science:	WOS:000397834900016
Scopus:	2-s2.0-85009496029
Chemical Abstracts:	2017:86181
Chemical Abstracts (print):	166:215676
OpenAlex:	W2568618859

DB	Citing
Scopus	15
Web of science	14
OpenAlex	14