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Synthesis and Structure of New Er(III) Complexes with N,N′-1,3-bis(2,6-Diisopropylphenyl)triazenide Full article

Journal Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779
Output data Year: 2021, Volume: 62, Number: 2, Pages: 277-284 Pages count : 8 DOI: 10.1134/s0022476621020128
Tags coordination compounds; lanthanides; erbium; triazenes; synthesis; crystal structure.
Authors Kolybalov D.S. 1,2 , Sukhikh T.S. 1 , Bashirov D.A. 1 , Konchenko S.N. 1
Affiliations
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2 Novosibirsk State University, Novosibirsk, Russia

Abstract: By the interaction of [Er(N(SiMe3)2)3] with HN3Dipp ((N3Dipp)– = N,N′-1,3-bis(2,6-diisopropylphenyl) triazenide) [Er(N3Dipp)(N(SiMe3)2)2] (1) and [Er(N3Dipp)2(N(SiMe3)2)] (2) complexes are obtained. The reaction of 2 with thiophenol gives [Er(N3Dipp)2(SPh)(THF)] complex (3). The structures of the compounds is determined by single crystal X-ray diffraction of the following solid phases: 1, 2·C6H6, and 3.
Cite: Kolybalov D.S. , Sukhikh T.S. , Bashirov D.A. , Konchenko S.N.
Synthesis and Structure of New Er(III) Complexes with N,N′-1,3-bis(2,6-Diisopropylphenyl)triazenide
Journal of Structural Chemistry. 2021. V.62. N2. P.277-284. DOI: 10.1134/s0022476621020128 WOS Scopus AN OpenAlex
Original: Колыбалов Д.С. , Сухих Т.С. , Баширов Д.А. , Конченко С.Н.
Синтез и строение новых комплексов Er(III) с N,N'‑1,3‑бис(2,6-диизопропилфенил)триазенидом
Журнал структурной химии. 2021. Т.62. №2. С.292-300. DOI: 10.26902/JSC_id68354 OpenAlex
Dates:
Submitted: Jun 30, 2020
Accepted: Jul 30, 2020
Published print: Feb 1, 2021
Published online: Mar 16, 2021
Identifiers:
Web of science: WOS:000629622600012
Scopus: 2-s2.0-85106245779
Chemical Abstracts: 2021:687434
OpenAlex: W3137580336
Citing:
DB Citing
Scopus 2
Web of science 1
OpenAlex 1
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