Synthesis and Structure of Heteroleptic Tm Bis(Formamidinate) Complexes Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2020, Volume: 61, Number: 4, Pages: 550-558 Pages count : 9 DOI: 10.1134/s0022476620040071 | ||||
| Tags | coordinate compounds, lanthanides, thulium, amidinates, formamidinates, synthesis, crystal structure. | ||||
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Abstract:
By the interaction of TmCl3 with KFormDipp (FormDipp = N,N′-bis(2,6-diisopropylphenyl)-
formamidinate) [Tm(FormDipp)2Cl(THF)] (1) and [KTm(FormDipp)2Cl2]2 (2) complexes are obtained. The
reaction of 1 with potassium thiophenolate is studied. Its product is found to be
[Tm(FormDipp)2(SPh)(THF)] complex (3). The structure of all prepared compounds is determined by
single crystal X-ray diffraction of the following solid phases: 1a (P–1) and 1b (P21/n) phases being two
solvent-free polymorphs for complex 1; 2⋅0.5C7H8 and 3⋅C7H8 phases containing solvate toluene molecules
for complexes 2 and 3.
Cite:
Bashirov D.A.
, Kolybalov D.S.
, Sukhikh T.S.
, Konchenko S.N.
Synthesis and Structure of Heteroleptic Tm Bis(Formamidinate) Complexes
Journal of Structural Chemistry. 2020. V.61. N4. P.550-558. DOI: 10.1134/s0022476620040071 WOS Scopus AN OpenAlex
Synthesis and Structure of Heteroleptic Tm Bis(Formamidinate) Complexes
Journal of Structural Chemistry. 2020. V.61. N4. P.550-558. DOI: 10.1134/s0022476620040071 WOS Scopus AN OpenAlex
Original:
Баширов Д.А.
, Колыбалов Д.С.
, Сухих Т.С.
, Конченко С.Н.
Синтез и строение гетеролептических бис-формамидинатных комплексов Tm
Журнал структурной химии. 2020. Т.61. №4. С.580-588. DOI: 10.26902/JSC_id54011 OpenAlex
Синтез и строение гетеролептических бис-формамидинатных комплексов Tm
Журнал структурной химии. 2020. Т.61. №4. С.580-588. DOI: 10.26902/JSC_id54011 OpenAlex
Dates:
| Submitted: | Sep 2, 2019 |
| Accepted: | Nov 11, 2019 |
| Published print: | Apr 1, 2020 |
| Published online: | Jul 29, 2020 |
Identifiers:
| Web of science: | WOS:000554783300007 |
| Scopus: | 2-s2.0-85088636181 |
| Chemical Abstracts: | 2020:1483714 |
| OpenAlex: | W3045974311 |