Young’s Modulus and Vickers Hardness of the Hydroxyapatite Bioceramics with a Small Amount of the Multi-Walled Carbon Nanotubes | Sciact - CRIS-system of Boreskov Institute of Catalysis

Young’s Modulus and Vickers Hardness of the Hydroxyapatite Bioceramics with a Small Amount of the Multi-Walled Carbon Nanotubes Full article

Journal

Materials
ISSN: 1996-1944

Output data

Year: 2022, Volume: 15, Number: 15, Article number : 5304, Pages count : 17 DOI: 10.3390/ma15155304

Tags

bioceramics; hydroxyapatite; multi-walled carbon nanotubes; Young’s modulus; compression strength; Vickers microhardness; plastic and elastic (reversible) works

Authors

Barabashko Maksym ¹ , Ponomarev Alexander ² , Rezvanova Anastasiya ² , Kuznetsov Vladimir ³ , Moseenkov Sergey ³

Affiliations

1	B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine (B. Verkin ILTPE of NASU), 47 Nauky Ave., 61103 Kharkiv, Ukraine
2	Institute of Strength Physics and Materials Science of Siberian Branch Russian Academy of Sciences (ISPMS SB RAS), 2/4, pr. Akademicheskii, 634055 Tomsk, Russia
3	Boreskov Institute of Catalysis of Siberian Branch Russian Academy of Sciences (SB RAS), 5, pr. Lavrentieva, 630090 Novosibirsk, Russia

Funding (2)

1	National Academy of Sciences of Ukraine	0119U102391
2	Ministry of Science and Higher Education of the Russian Federation	075-00739-22-01 (122040400067-4) (FWRW-2022-0002)

The Vickers hardness and Young’s modulus of the hydroxyapatite (HA) bioceramics with a small amount of the multi-walled carbon nanotubes (MWCNTs) were studied by using ultramicrotester Shimadzu for dynamic tests DUH-211. Small concentrations of MWCNTs were from 0.05 to 0.5 wt.%. The argon inert atmosphere and vacuum condition were taken for the prevention of the MWCNTs oxidation. The Brunauer–Emmett–Teller (BET) surface area SBET of the HA-MWCNTs composites was determined by thermal adsorption-desorption of nitrogen. It was found that for HA-MWCNTs sintered in the Ar atmosphere, an increase in the concentration of nanotubes up to 0.5 wt.% leads to a decrease in porosity near 3 times in comparison to HA without MWCNTs additives. The small amount of additives of multi-walled carbon nanotubes leads to an increase in hardness of 1.3 times and compression strength of composite and compression strength of composite that is comparable in absolute values with the literature data of enamel hardness (3–5 GPa) and compression strength (95–370 MPa). The absolute values increase close to linearly with the increase of nanotube concentrations. The Young’s modulus of sintered composite slightly changes with the variation of concentrations of nanotubes and close to the enamel (75–100 GPa). The ratio of plastic work to total work and the ratio of elastic (reversible) work to the total work of deformation of composite HA/MWCNTs are practically constant at a studied range of MWCNTs concentration. The additives of the multi-walled carbon nanotubes lead to both an increase in the elasticity index of ~1.5 times and an increase in the resistance to plastic deformation of ~3 times, which improved the tribological performance of the surface. Plastic and elastic (reversible) work slightly changed.

Barabashko M. , Ponomarev A. , Rezvanova A. , Kuznetsov V. , Moseenkov S.
Young’s Modulus and Vickers Hardness of the Hydroxyapatite Bioceramics with a Small Amount of the Multi-Walled Carbon Nanotubes
Materials. 2022. V.15. N15. 5304 :1-17. DOI: 10.3390/ma15155304 WOS Scopus РИНЦ AN PMID OpenAlex

Submitted:	Jun 20, 2022
Accepted:	Jul 28, 2022
Published print:	Aug 1, 2022

Web of science:	WOS:000839034600001
Scopus:	2-s2.0-85137149393
Elibrary:	50394486
Chemical Abstracts:	2022:2120938
PMID:	35955238
OpenAlex:	W4289313923

DB	Citing
Web of science	8
Scopus	9
Elibrary	7
OpenAlex	7