One-Pot Synthesis of Menthol Starting from Citral over Ni Supported on Attapulgite-H-Beta-38 Extrudates in a Continuous Flow: Effect of Metal Location Научная публикация
| Журнал |
Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045 |
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| Вых. Данные | Год: 2022, Том: 61, Номер: 35, Страницы: 12998–13010 Страниц : 13 DOI: 10.1021/acs.iecr.2c02345 | ||||||
| Ключевые слова | Catalysts, Diffraction, Metals, Nickel, Particle size | ||||||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 0239-2021-0008 |
| 2 | Academy of Finland |
Реферат:
The one-pot synthesis of menthol from citral in a continuous mode was investigated over three different types of extrudates, namely Ni supported on H-Beta-38 and extruded with attapulgite, Ni supported on attapulgite and extruded with H-Beta-38, and the extrudates, which were shaped after deposition of Ni on both H-Beta-38 and attapulgite in the powder form. These composite catalysts were characterized by X-ray diffraction, transmission and scanning electron microscopy, temperature-programmed reduction of H2, mechanical strength, and pyridine adsorption desorption. These three types of extrudates exhibited different metal particle sizes and acidity. The most promising catalyst in the one-pot menthol synthesis was Ni supported first on H-Beta-38 and then extruded with attapulgite giving a 45% yield of menthols in a trickle bed reactor. This catalyst exhibited 10 nm nickel particles and a rather high amount of strong Brønsted acid sites.
Библиографическая ссылка:
Simakova I.L.
, Mäki-Arvela P.
, Martínez-Klimov M.
, Muller J.
, Vajglová Z.
, Peurla M.
, Eränen K.
, Murzin D.Y.
One-Pot Synthesis of Menthol Starting from Citral over Ni Supported on Attapulgite-H-Beta-38 Extrudates in a Continuous Flow: Effect of Metal Location
Industrial and Engineering Chemistry Research. 2022. V.61. N35. P.12998–13010. DOI: 10.1021/acs.iecr.2c02345 WOS Scopus РИНЦ CAPlusCA OpenAlex
One-Pot Synthesis of Menthol Starting from Citral over Ni Supported on Attapulgite-H-Beta-38 Extrudates in a Continuous Flow: Effect of Metal Location
Industrial and Engineering Chemistry Research. 2022. V.61. N35. P.12998–13010. DOI: 10.1021/acs.iecr.2c02345 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 30 июн. 2022 г. |
| Принята к публикации: | 14 авг. 2022 г. |
| Опубликована online: | 25 авг. 2022 г. |
| Опубликована в печати: | 7 сент. 2022 г. |
Идентификаторы БД:
| Web of science: | WOS:000848752900001 |
| Scopus: | 2-s2.0-85137303752 |
| РИНЦ: | 50741550 |
| Chemical Abstracts: | 2022:2213057 |
| Chemical Abstracts (print): | 181:149208 |
| OpenAlex: | W4293243649 |