Hydrogen Production by Autothermal Reforming of Methane over NiPd Catalysts: Effect of Support Composition and Preparation Mode | Sciact - CRIS-система Института катализа

Hydrogen Production by Autothermal Reforming of Methane over NiPd Catalysts: Effect of Support Composition and Preparation Mode Научная публикация

Журнал

International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487

Вых. Данные

Год: 2014, Том: 39, Номер: 36, Страницы: 20969-20983 Страниц : 15 DOI: 10.1016/j.ijhydene.2014.10.044

Ключевые слова

Autothermal reforming, Bimetallic catalyst, Hydrogen production

Авторы

Ismagilov I.Z. ¹ , Matus E.V. ¹ , Kuznetsov V.V. ¹ , Kerzhentsev M.A. ¹ , Yashnik S.A. ¹ , Prosvirin I.P. ¹ , Mota N. ² , Navarro R.M. ² , Fierro G.J. ² , Ismagilov Z.R. ^1,3

Организации

1	Boreskov Institute of Catalysis SB RAS, Pr. Akademika Lavrentieva 5, 630090 Novosibirsk, Russia
2	Instituto de Catalisis y Petroleoquımica, CSIC, Marie Curie 2, 28049 Madrid, Spain
3	Institute of Coal Chemistry and Material Science SB RAS, Pr. Sovetskiy 18, 650000 Kemerovo, Russia

Информация о финансировании (1)

European Commission

262840 FP7-NMP-2010-LARGE-4 DEMCAMER

NiPd/Ce0.5Zr0.5O2/Al2O3 and NiPd/La2O3/Ce0.5Zr0.5O2/Al2O3 catalysts were prepared by incipient wetness co-impregnation method or sequential impregnation method for autothermal reforming of methane (ATR of CH4). The influence of the preparation mode, Ce0.5Zr0.5O2 and La2O3 additives on the physicochemical properties of NiPd supported catalysts and the effect on their activity to produce hydrogen by ATR of CH4 were investigated. Characterization of fresh and spent Ni-based catalysts by X-ray fluorescence spectroscopy, N2 adsorption, X-ray diffraction, H2 temperature-programmed reduction, high-resolution transmission electron microscopy and X-ray photoelectron spectroscopy were performed. It was demonstrated that support composition determines NiO dispersion as well as reducibility of Ni species through different strength of Ni-support interaction. The preparation method modifies the phase composition and catalyst ability for reduction. The catalyst evolution under reaction conditions was studied. The NiO (∼15 nm) and NiPd alloy (∼18 nm) phases were observed in the spent catalysts. It was found that the Nio/NiO ratio can be regulated by support composition and preparation mode of catalysts. It is demonstrated that studied catalysts provide high methane conversion of 90–100%, CO yield of 55–85% and H2 yield of 55–75% in ATR of CH4 at 750–950 °C. The optimal composition and preparation method of catalyst were selected. The best ATR of CH4 performance is provided by 10 Ni0.5Pd/10Ce0.5Zr0.5O2/Al2O3 catalyst prepared by Pd/Ni sequential impregnation method that can be associated with peculiarity of NiPd particles structure and the optimal ratio between NiO species with different ability for reduction.

Ismagilov I.Z. , Matus E.V. , Kuznetsov V.V. , Kerzhentsev M.A. , Yashnik S.A. , Prosvirin I.P. , Mota N. , Navarro R.M. , Fierro G.J. , Ismagilov Z.R.
Hydrogen Production by Autothermal Reforming of Methane over NiPd Catalysts: Effect of Support Composition and Preparation Mode
International Journal of Hydrogen Energy. 2014. V.39. N36. P.20969-20983. DOI: 10.1016/j.ijhydene.2014.10.044 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	13 июл. 2014 г.
Принята к публикации:	10 окт. 2014 г.
Опубликована online:	7 нояб. 2014 г.
Опубликована в печати:	12 дек. 2014 г.

Web of science:	WOS:000347576200014
Scopus:	2-s2.0-84937892593
РИНЦ:	23870705
Chemical Abstracts:	2014:1838166
Chemical Abstracts (print):	161:756335
OpenAlex:	W2074922876

БД	Цитирований
Web of science	55
Scopus	49
РИНЦ	59
OpenAlex	49