Catalytic Activity of LaFe0.4Ni0.6O3/CeO2 Composites in CO and CH4 Oxidation Depending on Their Preparation Conditions Научная публикация
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Materials
ISSN: 1996-1944 |
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| Вых. Данные | Год: 2023, Том: 16, Номер: 3, Номер статьи : 1142, Страниц : 14 DOI: 10.3390/ma16031142 | ||
| Ключевые слова | LaFe0.4Ni0.6O3/CeO2 composites; preparation; methane; CO oxidation | ||
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Информация о финансировании (1)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 0239-2021-0004 |
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Open AccessArticle
Catalytic Activity of LaFe0.4Ni0.6O3/CeO2 Composites in CO and CH4 Oxidation Depending on Their Preparation Conditions
by Lyubov Isupova *ORCID,Evgeny GerasimovORCID,Igor ProsvirinORCID andVladimir Rogov
Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia
*
Author to whom correspondence should be addressed.
Materials 2023, 16(3), 1142; https://doi.org/10.3390/ma16031142
Received: 11 January 2023 / Revised: 25 January 2023 / Accepted: 27 January 2023 / Published: 29 January 2023
(This article belongs to the Special Issue New Advances in Heterogeneous Catalysis Materials)
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Abstract
LaFe0.4Ni0.6O3/CeO2 (1:1) two-phase composite materials were prepared by mechanochemical (MC) and Pechini routes. The catalytic properties of the composites in methane and CO oxidation reactions strongly depend on their preparation conditions. In low-temperature (<600 °C) catalytic CO oxidation the composites demonstrate a higher activity compared with LaFe0.4Ni0.6O3 perovskite. The highest activity was observed for the composite prepared by mechanical treatment of perovskite and fluorite precursors. There is a correlation between activity and the content of weakly bound surface oxygen species. Catalytic activity in high-temperature (>750 °C) catalytic methane oxidation correlates with the reducibility of samples. The highest activity was observed for the composite prepared by the one-pot Pechini route with higher reducibility of the sample up to 600 °C.
Библиографическая ссылка:
Isupova L.
, Gerasimov E.
, Prosvirin I.
, Rogov V.
Catalytic Activity of LaFe0.4Ni0.6O3/CeO2 Composites in CO and CH4 Oxidation Depending on Their Preparation Conditions
Materials. 2023. V.16. N3. 1142 :1-14. DOI: 10.3390/ma16031142 WOS Scopus РИНЦ CAPlus PMID OpenAlex
Catalytic Activity of LaFe0.4Ni0.6O3/CeO2 Composites in CO and CH4 Oxidation Depending on Their Preparation Conditions
Materials. 2023. V.16. N3. 1142 :1-14. DOI: 10.3390/ma16031142 WOS Scopus РИНЦ CAPlus PMID OpenAlex
Даты:
| Поступила в редакцию: | 11 янв. 2023 г. |
| Принята к публикации: | 27 янв. 2023 г. |
| Опубликована online: | 29 янв. 2023 г. |
| Опубликована в печати: | 1 февр. 2023 г. |
Идентификаторы БД:
| Web of science: | WOS:000935708900001 |
| Scopus: | 2-s2.0-85147999627 |
| РИНЦ: | 53957583 |
| Chemical Abstracts: | 2023:315401 |
| PMID (PubMed): | 36770148 |
| OpenAlex: | W4318464999 |
Цитирование в БД:
| БД | Цитирований |
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| РИНЦ | 1 |