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Probing Light Hydrocabons Mobility by 2H NMR in Nanoporous UiO-66 MOF: Effects of Inorganic Centers Hydroxylation and Framework Defecfs Conference Abstracts

Conference 15th International Bologna Conference on Magnetic Resonance in Porous Media
21-26 Aug 2022 , Hangzhou
Source 15th International Bologna Conference on Magnetic Resonance in Porous Media (MRPM15)
Compilation, ZJU. China.2022. 163 c.
Output data Year: 2022, Pages: 105 Pages count : 1
Authors Khudozhitkov Alexander E. 1,2 , Stepanov Alexander G. 1 , Kolokolov Daniil I. 1,3
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Lavrentyeva 5, 630090 Novosibirsk, Russia
2 Novosibirsk State University, Pirogova 1, 630090 Novosibirsk, Russia
3 Universität Rostock, Institut für Chemie, Albert-Einstein-Straße 27, 18059 Rostock, Germany

Funding (2)

1 Ministry of Science and Higher Education of the Russian Federation 0239-2021-0003
2 Russian Foundation for Basic Research 19-33-90026 (АААА-А19-119100390010-3)

Abstract: The porous metal-organic frameworks (MOFs) are currently regarded as one of the main platforms for energy efficient solutions in such important industrial tasks as hydrocarbon mixtures separation, CO2 sequestration and heterogenous catalysis. These processes are greatly dependent on the guest-host interaction of the adsorbed species with the hosting framework. In case of MOFs the guest host interactions are influenced by the presence of active sites, like open metal centers, capable to form hydrogen bonds functional groups (i.e. OH species) and the potential presence of defects.
Cite: Khudozhitkov A.E. , Stepanov A.G. , Kolokolov D.I.
Probing Light Hydrocabons Mobility by 2H NMR in Nanoporous UiO-66 MOF: Effects of Inorganic Centers Hydroxylation and Framework Defecfs
In compilation 15th International Bologna Conference on Magnetic Resonance in Porous Media (MRPM15). – ZJU., 2022. – C.105.
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Citing: Пока нет цитирований