Ionic Liquids—New Gas Chromatographic Phases with Unique Properties. A Review Review
| Journal |
Doklady Physical Chemistry
ISSN: 0012-5016 , E-ISSN: 1608-3121 |
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| Output data | Year: 2023, Volume: 508, Number: 1, Pages: 1–16 Pages count : 16 DOI: 10.1134/S0012501623600018 | ||||
| Tags | gas–liquid chromatography; ionic liquids; thermal stability; highly polar liquid phases; selectivity | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0003 |
Abstract:
A necessary and the most difficult element in the study of many chemical processes is a reliable chemical analysis of both the initial reagents and the products of their transformation. One of the most common methods for such analysis is capillary gas chromatography, which, unfortunately, has some limitations. The limitations include, for example, the low thermal stability of high polarity stationary liquid phases (SLPs). A way to overcome this limitation is the use of ionic liquids (ILs) as SLPs. In this review, we focus on the use of liquid phases based on ILs with cations of various chemical classes. The properties of such SLPs are considered from the point of view of their possible chromatographic selectivity, and examples of the use of columns with ILs for solving specific analytical problems are given. The properties of currently available commercial columns where ILs are used as the SLPs are discussed.
Cite:
Shashkov M.V.
, Sidelnikov V.N.
, Parmon V.N.
Ionic Liquids—New Gas Chromatographic Phases with Unique Properties. A Review
Doklady Physical Chemistry. 2023. V.508. N1. P.1–16. DOI: 10.1134/S0012501623600018 WOS Scopus РИНЦ AN OpenAlex
Ionic Liquids—New Gas Chromatographic Phases with Unique Properties. A Review
Doklady Physical Chemistry. 2023. V.508. N1. P.1–16. DOI: 10.1134/S0012501623600018 WOS Scopus РИНЦ AN OpenAlex
Original:
Шашков М.В.
, Сидельников В.Н.
, Пармон В.Н.
Ионные жидкости – новые газохроматографические фазы с уникальными свойствами. Обзор
Доклады Российской академии наук. Химия, науки о материалах (Доклады Академии наук до 2019 года). 2023. Т.508. №1. С.79-96. DOI: 10.31857/S2686953522600556 РИНЦ OpenAlex
Ионные жидкости – новые газохроматографические фазы с уникальными свойствами. Обзор
Доклады Российской академии наук. Химия, науки о материалах (Доклады Академии наук до 2019 года). 2023. Т.508. №1. С.79-96. DOI: 10.31857/S2686953522600556 РИНЦ OpenAlex
Dates:
| Submitted: | Aug 17, 2022 |
| Accepted: | Oct 12, 2022 |
| Published print: | Jan 1, 2023 |
| Published online: | May 24, 2023 |
Identifiers:
| Web of science: | WOS:000993856400001 |
| Scopus: | 2-s2.0-85160024829 |
| Elibrary: | 54385696 |
| Chemical Abstracts: | 2023:1073551 |
| OpenAlex: | W4377724714 |