Development of Highly Efficient Hydroisodeparaffinization Catalysts Based on Micro-Mesoporous SAPO-31: New Approaches in the Synthesis of SAPO-31 and the Preparation of Bifunctional Catalysts Full article
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Catalysts
ISSN: 2073-4344 |
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| Output data | Year: 2023, Volume: 13, Number: 5, Article number : 810, Pages count : 11 DOI: 10.3390/catal13050810 | ||
| Tags | SAPO-31; silicoalumophosphate; Stöber process; tetraethoxysilane; micro-mesoporous materials; bifunctional hydroisodeparaffinization catalysts | ||
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0014 |
Abstract:
A method is proposed for the synthesis of micro-mesoporous SAPO-31 with a high external surface area and large mesopore volume using tetraethoxysilane as a source of silicon. The synthesis of SAPO-31 is based on the principles underlying the Stöber process approach, which allows control of the pore diameter and volume and, hence, the external surface area of the product material. The use of the proposed methods for depositing the hydro-dehydrogenating component on the synthesized micro-mesoporous SAPO-31 made it possible to obtain highly efficient bifunctional hydroisodeparaffinization catalysts with the platinum or palladium content not higher than 0.2 wt.%. As a result, the process temperature can be decreased by 50–60 °C in comparison with the known analogs. Therewith, for example, in the test reaction of n-decane hydroisodeparaffinization at a temperature of 300 °C and feed rate of 1.5 h−1, the conversion above 90%, and the 97–98% yield of liquid products, the 95% selectivity to isomeric products were achieved.
Cite:
Echevsky G.V.
, Toktarev A.V.
, Kodenev E.G.
, Aksenov D.G.
Development of Highly Efficient Hydroisodeparaffinization Catalysts Based on Micro-Mesoporous SAPO-31: New Approaches in the Synthesis of SAPO-31 and the Preparation of Bifunctional Catalysts
Catalysts. 2023. V.13. N5. 810 :1-11. DOI: 10.3390/catal13050810 WOS Scopus РИНЦ AN OpenAlex
Development of Highly Efficient Hydroisodeparaffinization Catalysts Based on Micro-Mesoporous SAPO-31: New Approaches in the Synthesis of SAPO-31 and the Preparation of Bifunctional Catalysts
Catalysts. 2023. V.13. N5. 810 :1-11. DOI: 10.3390/catal13050810 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Feb 27, 2023 |
| Accepted: | Apr 22, 2023 |
| Published online: | Apr 27, 2023 |
| Published print: | May 1, 2023 |
Identifiers:
| Web of science: | WOS:000996791700001 |
| Scopus: | 2-s2.0-85160790592 |
| Elibrary: | 54385185 |
| Chemical Abstracts: | 2023:1134723 |
| OpenAlex: | W4367316211 |
Citing:
| DB | Citing |
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| OpenAlex | 1 |