A Comprehensive Study on in situ Synthesis of a Magnetic Nanocomposite of Magnetite and Reduced Graphene Oxide and Its Effectiveness at Removing Arsenic from Water | Sciact - CRIS-system of Boreskov Institute of Catalysis

A Comprehensive Study on in situ Synthesis of a Magnetic Nanocomposite of Magnetite and Reduced Graphene Oxide and Its Effectiveness at Removing Arsenic from Water Full article

Journal

Nano-Structures and Nano-Objects
, E-ISSN: 2352-507X

Output data

Year: 2023, Volume: 36, Article number : 101028, Pages count : 18 DOI: 10.1016/j.nanoso.2023.101028

Tags

Nanocomposite; Magnetite nanoparticle; Reduced graphene oxide; Adsorption capacity; Water purification; Pollution removal

Authors

Pryadko Artyom ¹ , Mukhortova Yulia R. ¹ , Botvin Vladimir V. ² , Grubova Irina Y. ¹ , Galstenkova Maria R. ¹ , Wagner Dmitry V. ³ , Gerasimov Evgeny Y. ⁴ , Sukhinina Ekaterina V. ^5,6 , Pershina Alexandra G. ^5,6 , Kholkin Andrei L. ^2,7 , Surmeneva Maria A. ^1,2 , Surmenev Roman A. ^1,2

Affiliations

1	Physical Materials Science and Composite Materials Center, Research School of Chemistry & Applied Biomedical Sciences, National Research Tomsk Polytechnic University, Tomsk 634050, Russia
2	International Research & Development Center Piezo- and Magnetoelectric Materials, Research School of Chemistry & Applied Biomedical Sciences, National Research Tomsk Polytechnic University, Tomsk 634050, Russia
3	National Research Tomsk State University, Tomsk 634050, Russia
4	Department of Catalyst Research, Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russia
5	Center of Bioscience & Bioengineering, Siberian State Medical University, Tomsk 634050, Russia
6	Research School of Chemistry & Applied Biomedical Sciences, National Research Tomsk Polytechnic University, Tomsk 634050, Russia
7	Institute of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg 620026, Russia

Funding (4)

1	Ministry of Science and Higher Education of the Russian Federation	075-15-2021-588
2	Russian Science Foundation	22-13-20043 (122032900065-0)
3	Russian Science Foundation	20-63-47096 (АААА-А20-120052690025-2)
4	Ministry of Science and Higher Education of the Russian Federation	075-15-2021-677

In this study, the in situ synthesis of Fe3O4 nanoparticles on the surface of two-dimensional rGO nanosheets was performed. Fe3O4/rGO nanocomposites with a different degree of rGO reduction were obtained using various mass ratios between Fe3O4 and rGO, and different synthesis times. A comprehensive analysis of the morphology, microstructure, magnetic properties and the reduction degree of the synthesized rGO and Fe3O4/rGO nanocomposites was performed. The synthesis conditions were established for the preparation of a Fe3O4/rGO nanocomposite with the highest degree of rGO reduction and Fe3O4 phase purity. An increase in crystallite size and average particle size with the increase in the Fe3O4:rGO mass ratio (from 1:1 to 6:1) was revealed. For the first time, a saturation point for the amount of phase-pure Fe3O4 nanoparticles on the rGO surface was determined, as was a specific ratio of magnetite to rGO at which saturation occurred. Examination of the adsorption isotherms and kinetics indicated that the magnetic Fe3O4/rGO nanocomposite can serve as an effective adsorbent for arsenic ion (As3+) removal from water, with an excellent removal capacity of 14 mg g−1. In addition, the adsorption rate of the Fe3O4/rGO nanocomposite enabled 81% uptake within 1 min, which is superior to the literature data.

Pryadko A. , Mukhortova Y.R. , Botvin V.V. , Grubova I.Y. , Galstenkova M.R. , Wagner D.V. , Gerasimov E.Y. , Sukhinina E.V. , Pershina A.G. , Kholkin A.L. , Surmeneva M.A. , Surmenev R.A.
A Comprehensive Study on in situ Synthesis of a Magnetic Nanocomposite of Magnetite and Reduced Graphene Oxide and Its Effectiveness at Removing Arsenic from Water
Nano-Structures and Nano-Objects. 2023. V.36. 101028 :1-18. DOI: 10.1016/j.nanoso.2023.101028 Scopus РИНЦ ANCAN OpenAlex

Submitted:	May 13, 2023
Accepted:	Aug 2, 2023
Published online:	Aug 26, 2023
Published print:	Oct 23, 2023

Scopus:	2-s2.0-85168811344
Elibrary:	55990756
Chemical Abstracts:	2023:1861799
Chemical Abstracts (print):	184:123655
OpenAlex:	W4386197258

DB	Citing
OpenAlex	9
Scopus	8
Elibrary	7