Zinc(II) and Nickel(II) Complexes with N-[2-(2-diethylphoshponylethyliminomethyl)phenyl]-4-methylbenzenesulfonamide: Synthesis, Structure, and Photoluminescence Properties | Sciact - CRIS-система Института катализа

Zinc(II) and Nickel(II) Complexes with N-[2-(2-diethylphoshponylethyliminomethyl)phenyl]-4-methylbenzenesulfonamide: Synthesis, Structure, and Photoluminescence Properties Научная публикация

Журнал

Inorganica Chimica Acta
ISSN: 0020-1693 , E-ISSN: 1873-3255

Вых. Данные

Год: 2023, Том: 558, Номер статьи : 121765, Страниц : 10 DOI: 10.1016/j.ica.2023.121765

Ключевые слова

Azomethines, Zinc and nickel complexes, UV–Vis spectra, Photoluminescence, Synchrotron single-crystal X-ray diffraction

Авторы

Burlov Anatolii S. ¹ , Vlasenko Valery G. ² , Popov Leonid D. ³ , Koshchienko Yurii V. ¹ , Garnovskii Dmitrii A. ⁴ , Kolodina Alexandra A. ¹ , Korshunova Evgeniya V. ¹ , Zubavichus Yan V. ⁵ , Lazarenko Vladimir A. ⁶

Организации

1	Southern Federal University, Institute of Physical and Organic Chemistry, Stachki ave. 194/2, 344090 Rostov-on-Don, Russian Federation
2	Southern Federal University, Institute of Physics, Stachki ave. 194, 344090 Rostov-on-Don, Russian Federation
3	Southern Federal University, Department of Chemistry, Zorge st. 7, 344090 Rostov-on-Don, Russian Federation
4	Southern Scientific Center of Russian Academy of Sciences, 41 Chekhova str., 344006 Rostov-on-Don, Russian Federation
5	Synchrotron Radiation Facility SKIF, Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Nikolskii pr., 1, 630559 Koltsovo, Russian Federation
6	National Research Center «Kurchatov Institute», Acad. Kurchatov Sq. 1, 123182 Moscow, Russian Federation

Информация о финансировании (2)

1	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	ГЗ-2021-2023
2	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	FENW-2023-0011

Two Zn(II) and Ni(II) complexes derived from the N-[2-(2-diethylphosphonylethyliminomethyl)phenyl]-4-methylbenzenesulfonamide ligand (HL) with stoichiometry ML2 (M = Zn, Ni) have been synthesized. Their structures have been established using elemental analysis, IR, 1H NMR, UV–Vis spectroscopy, and synchrotron single-crystal X-ray diffraction. The Zn(II) and Ni(II) metal sites therein adopt the tetrahedral configuration. The DMSO and toluene solutions of the Zn(II) complex manifest photoluminescence in the blue-violet spectral range characterized by PL maxima at 436 and 432 nm and quantum yields of 0.15 and 0.30, respectively.

Burlov A.S. , Vlasenko V.G. , Popov L.D. , Koshchienko Y.V. , Garnovskii D.A. , Kolodina A.A. , Korshunova E.V. , Zubavichus Y.V. , Lazarenko V.A.
Zinc(II) and Nickel(II) Complexes with N-[2-(2-diethylphoshponylethyliminomethyl)phenyl]-4-methylbenzenesulfonamide: Synthesis, Structure, and Photoluminescence Properties
Inorganica Chimica Acta. 2023. V.558. 121765 :1-10. DOI: 10.1016/j.ica.2023.121765 WOS Scopus РИНЦ CAPlus OpenAlex СКИФ ID

Поступила в редакцию:	10 июл. 2023 г.
Принята к публикации:	12 сент. 2023 г.
Опубликована online:	14 сент. 2023 г.
Опубликована в печати:	1 дек. 2023 г.

Web of science:	WOS:001081500400001
Scopus:	2-s2.0-85171474371
РИНЦ:	64934359
Chemical Abstracts:	2023:1959042
OpenAlex:	W4386701169
СКИФ ID:	590

Пока нет цитирований