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Two New Bismuth Salts with Succinic Acid: Synthesis, Structural, Spectroscopic and Thermal Characterization Full article

Journal Acta Crystallographica Section C
, E-ISSN: 2053-2296
Output data Year: 2023, Volume: 79, Number: 10, Pages: 409-416 Pages count : 8 DOI: 10.1107/s2053229623008124
Tags bis­muth com­pound; crystal structure; succinic acid; active pharmaceutical ingredient; API; IR spectroscopy; Raman spectroscopy; thermal analysis.
Authors Timakova Evgeniya V. 1,2 , Afonina L.I. 1,2 , Drebushchak T.N. 1 , Zakharov Boris A. 3,4
Affiliations
1 Institute of Solid State Chemistry and Mechanochemistry, SB RAS, Kutateladze 18, Novosibirsk 630128, Russian Federation
2 Novosibirsk State Technical University, Prospekt K. Marksa 20, Novosibirsk, 630073, Russian Federation
3 Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russian Federation
4 Boreskov Institute of Catalysis, SB RAS, Lavrentieva Avenue 5, Novosibirsk 630090, Russian Federation

Funding (2)

1 Ministry of Science and Higher Education of the Russian Federation 0239-2021-0002
2 Ministry of Science and Higher Education of the Russian Federation 075-00521-21-00 (121032500064-8) (FWUS-2021-0009)

Abstract: Two novel bis­muth succinate hydrates, namely, poly[[di­aqua­(μ3-butane-1,4-di­carboxyl­ato)hemi(μ-butane-1,4-di­carboxyl­ato)bis­muth] monohydrate], {[Bi(C4H4O4)1.5(H2O)2]·H2O}n (1), and poly[[μ-aqua-aqua­(μ3-butane-1,4-di­car­box­yl­ato)(μ-butane-1,4-di­carboxyl­ato)-μ-oxido-dibismuth] monohydrate], {[Bi2(C4H4O4)2O(H2O)2]·H2O}n (2), have been synthesized. Their crystal structures were determined by single-crystal X-ray diffraction and the compounds were characterized by IR and Raman spectroscopy, powder X-ray diffraction and thermal analysis. The crystal structure analysis revealed that the com­pounds are coordination polymers, with 1 having a two-dimensional layered structure and 2 displaying a three-dimensional (3D) framework. Fully deprotonated succinate anions (C4H4O42−) in two different conformations (trans and gauche) are included in their com­position. The Bi3+ cations are surrounded by O atoms from the carboxyl­ate groups of succinate anions and aqua ligands. BiO9 coordination polyhedra in 1 are connected in pairs by edges. These pairs are bound together by bridging succinate ligands to form layers. Bis­muth coordination polyhedra of two different types (BiO9 and BiO7) in 2 are connected by edges to form infinite ribbons. Ribbons of polyhedra with bridging succinate ligands form a 3D polymeric structure.
Cite: Timakova E.V. , Afonina L.I. , Drebushchak T.N. , Zakharov B.A.
Two New Bismuth Salts with Succinic Acid: Synthesis, Structural, Spectroscopic and Thermal Characterization
Acta Crystallographica Section C. 2023. V.79. N10. P.409-416. DOI: 10.1107/s2053229623008124 WOS Scopus РИНЦ AN PMID OpenAlex
Dates:
Submitted: Jan 26, 2023
Accepted: Sep 16, 2023
Published online: Sep 21, 2023
Published print: Oct 1, 2023
Identifiers:
Web of science: WOS:001086804800004
Scopus: 2-s2.0-85174535233
Elibrary: 54905261
Chemical Abstracts: 2023:2059635
PMID: 37733617
OpenAlex: W4386911169
Citing: Пока нет цитирований
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