Single-Atom Alloy Pd1Ag10/Al2O3 Catalyst: Effect of CO-Induced Pd Surface Segregation on the Structure and Catalytic Performance in the Hydrogenation of C2H2 | Sciact - CRIS-system of Boreskov Institute of Catalysis

Single-Atom Alloy Pd1Ag10/Al2O3 Catalyst: Effect of CO-Induced Pd Surface Segregation on the Structure and Catalytic Performance in the Hydrogenation of C2H2 Full article

Journal

Mendeleev Communications
ISSN: 0959-9436 , E-ISSN: 1364-551X

Output data

Year: 2023, Volume: 33, Pages: 812-814 Pages count : 3 DOI: 10.1016/j.mencom.2023.10.024

Tags

single-atom alloy catalyst, adsorption-induced segregation, CO adsorption, selective acetylene hydrogenation, Pd, DRIFTS, XPS

Authors

Markov Pavel V. ¹ , Smirnova Nadezhda S. ¹ , Baeva Galina N. ¹ , Mashkovsky Igor S. ¹ , Bukhtiyarov Andrey V. ² , Chetyrin Igor A. ² , Zubavichus Yan V. ² , Stakheev Alexander Yu. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

Funding (1)

Russian Science Foundation

19-13-00285-П

The effective surface concentration of Pd1 sites composed of individual palladium atoms isolated from each other by Ag atoms in the Pd1Ag10 /Al2O3 single-atom alloy (SAA) catalyst can be significantly enhanced by the adsorption-induced surface segregation upon a special pretreatment of the catalyst in a CO-containing atmosphere at 200 °C. The catalyst activity towards acetylene hydrogenation gets tripled without sacrificing selectivity for ethylene. The segregated surface of the catalyst is thus preserved under target reaction conditions.

Markov P.V. , Smirnova N.S. , Baeva G.N. , Mashkovsky I.S. , Bukhtiyarov A.V. , Chetyrin I.A. , Zubavichus Y.V. , Stakheev A.Y.
Single-Atom Alloy Pd1Ag10/Al2O3 Catalyst: Effect of CO-Induced Pd Surface Segregation on the Structure and Catalytic Performance in the Hydrogenation of C2H2
Mendeleev Communications. 2023. V.33. P.812-814. DOI: 10.1016/j.mencom.2023.10.024 WOS Scopus РИНЦ AN OpenAlex

Submitted:

Aug 9, 2023

Web of science:	WOS:001128148300001
Scopus:	2-s2.0-85183708712
Elibrary:	62786347
Chemical Abstracts:	2023:2659124
OpenAlex:	W4389123610

DB	Citing
OpenAlex	4
Web of science	5
Scopus	5
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