Zn-BTC MOF as Self-Template to Hierarchical ZnS/NiS2 Heterostructure with Improved Electrochemical Performance for Hybrid Supercapacitor | Sciact - CRIS-system of Boreskov Institute of Catalysis

Zn-BTC MOF as Self-Template to Hierarchical ZnS/NiS2 Heterostructure with Improved Electrochemical Performance for Hybrid Supercapacitor Full article

Journal

Nanomaterials
, E-ISSN: 2079-4991

Output data

Year: 2024, Volume: 14, Number: 1, Article number : 22, Pages count : 14 DOI: 10.3390/nano14010022

Tags

metal organic framework; metal sulfide; heterostructure; supercapacitor

Authors

Li Xuan ¹ , Liu Lingran ¹ , Tu Chengyu ¹ , Zhang Quan ^2,3 , Yang Xinchun ² , Kolokolov Daniil I. ⁴ , Maltanava Hanna ⁵ , Belko Nikita ⁵ , Poznyak Sergey ⁵ , Samtsov Michael ⁵ , Guo Haixin ⁶ , Wu Shuping ¹ , Zhu Maiyong ¹

Affiliations

1	Research School of Polymeric Materials, School of Materials Science & Engineering, Jiangsu University, Zhenjiang 212013, China
2	State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
3	Clean Energy Joint International Laboratory, Low-Dimensional Energy Materials Research Center, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China
4	Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Novosibirsk 630090, Russia
5	Research Institute for Physical Chemical Problems, Belarusian State University, Leningradskaya Str. 14, 220006 Minsk, Belarus
6	Agro-Environmental Protection Institute, Ministry of Agriculture and Rural Affairs, No. 31 Fukang Road, Nankai District, Tianjin 300191, China

Zn-BTC (H3BTC refers to 1, 3, 5-benzoic acid) MOF was used as a self-template and a zinc source to prepare ZnS/NiS2 with a layered heterogeneous structure as a promising electrode material using cation exchange and solid-phase vulcanization processes. The synergistic effect of the two metal sulfides enhances the application of ZnS/NiS2. And the high specific surface area and abundant active sites further promote the mass/charge transfer and redox reaction kinetics. In the three-electrode system, the specific capacitance was as high as 1547 F/g at a current density of 1 A/g, along with satisfactory rate capability (1214 F/g at 6 A/g) and cycling performance. Coupled with activated carbon (AC), the prepared hybrid device (ZnS/NiS2 as the positive electrode and AC as the negative electrode) (ZnS/NiS2/AC) can be operated under a potential window of 1.6 V and provides a high energy density of 26.3 Wh/kg at a power density of 794 W/kg. Notably, the assembled ZnS/NiS2//AC showed little capacity degradation after 5000 charge/discharge cycles.

Li X. , Liu L. , Tu C. , Zhang Q. , Yang X. , Kolokolov D.I. , Maltanava H. , Belko N. , Poznyak S. , Samtsov M. , Guo H. , Wu S. , Zhu M.
Zn-BTC MOF as Self-Template to Hierarchical ZnS/NiS2 Heterostructure with Improved Electrochemical Performance for Hybrid Supercapacitor
Nanomaterials. 2024. V.14. N1. 22 :1-14. DOI: 10.3390/nano14010022 WOS Scopus РИНЦ AN PMID OpenAlex

Submitted:	Nov 15, 2023
Accepted:	Dec 19, 2023
Published online:	Dec 20, 2023
Published print:	Jan 1, 2024

Web of science:	WOS:001141547200001
Scopus:	2-s2.0-85181876129
Elibrary:	64710981
Chemical Abstracts:	2024:137347
PMID:	38202477
OpenAlex:	W4389991527

DB	Citing
OpenAlex	6
Scopus	10
Web of science	9
Elibrary	6