Development of Supported Nickel-Cerium Catalysts for Resource-Saving Conversion of Methane into Hydrogen-Containing Gas Научная публикация
Журнал |
Chemistry for Sustainable Development
ISSN: 1817-1818 |
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Вых. Данные | Год: 2023, Том: 31, Номер: 5, Страницы: 552-560 Страниц : 9 DOI: 10.15372/CSD2023500 | ||
Ключевые слова | catalyst, methane, steam-carbon dioxide reforming, hydrogen | ||
Авторы |
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Организации |
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Реферат:
To develop an effective catalyst for the resource-saving conversion of coal-industry methane into hydrogen-containing gas, the materials Ce0.2Ni0.8O1.2/Al2O3 were synthesized, their physicochemical and functional properties were studied depending on the nature of the precursors of active components (nickel(II) nitrate hexahydrate, nickel(II) ammonium oxide) and promoters (cerium(III) nitrate hexahydrate, ammonium cerium(IV) nitrate). It is shown that the nature of the precursor affects the textural and structural characteristics of the samples, their catalytic activity in the steam-carbon dioxide reforming of methane and resistance to the formation of carbon deposits. The optimal composition of precursors (nickel (II) nitrate hexahydrate, cerium(III) nitrate hexahydrate) has been established, the use of which in the synthesis of the Ce0.2Ni0.8O1.2/Al2O3 catalyst ensures a decrease in the average particle size of the Ni active component (25 → 6.5 nm) and the degree of catalyst carbonisation (2.9 → 0.5%), high hydrogen yield (95%) at 800 °C in the steam-carbon dioxide reforming of methane.
Библиографическая ссылка:
Nikitin A.P.
, Sozinov S.A.
, Matus E.V.
, Ismagilov Z.R.
Development of Supported Nickel-Cerium Catalysts for Resource-Saving Conversion of Methane into Hydrogen-Containing Gas
Chemistry for Sustainable Development. 2023. V.31. N5. P.552-560. DOI: 10.15372/CSD2023500 WOS РИНЦ OpenAlex
Development of Supported Nickel-Cerium Catalysts for Resource-Saving Conversion of Methane into Hydrogen-Containing Gas
Chemistry for Sustainable Development. 2023. V.31. N5. P.552-560. DOI: 10.15372/CSD2023500 WOS РИНЦ OpenAlex
Оригинальная:
Никитин А.П.
, Созинов С.А.
, Матус Е.В.
, Исмагилов З.Р.
Разработка нанесенных никель-цериевых катализаторов для ресурсосберегающей конверсии метана в водородсодержащий газ
Химия в интересах устойчивого развития. 2023. Т.31. №5. С.568–575. DOI: 10.15372/KhUR202350 РИНЦ
Разработка нанесенных никель-цериевых катализаторов для ресурсосберегающей конверсии метана в водородсодержащий газ
Химия в интересах устойчивого развития. 2023. Т.31. №5. С.568–575. DOI: 10.15372/KhUR202350 РИНЦ
Идентификаторы БД:
Web of science: | WOS:001155670300001 |
РИНЦ: | 59071768 |
OpenAlex: | W4403693538 |