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Comparative Research of Pyrolysis of Light Alkanes (Methane and Ethane) on the Resistive FeCrAl Catalyst Full article

Conference Oil and Gas Engineering
26-29 Feb 2020 , Омск
Journal AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616
Output data Year: 2019, Volume: 2141, Article number : 020026, Pages count : 6 DOI: 10.1063/1.5122045
Authors Sigaeva S.S. 1 , Anoshkina E.A. 1 , Temerev V.L. 1 , Shlyapin D.A. 1
Affiliations
1 Center of New Chemical Technologies BIC, 54, Neftezavodskaya St., 644040 Omsk, Russia

Funding (1)

1 Federal Agency for Scientific Organizations V.46.2.5. (АААА-А17-117021450096-8)

Abstract: Methane and ethane pyrolysis on the FeCrAl alloy, as a catalyst, in the conditions of its resistive heating is investigated. The cold gas mixture consisting of methane (or ethane) and nitrogen was fed to a spiral heated by an electric current to 900-1300°C. As a result of experiments it is shown that pyrolysis of methane proceeds in two temperature zones with primary formation of ethane and ethylene - in the first and acetylene - in the second. Unlike methane, pyrolysis of ethane proceeds with primary formation of ethylene in the range of 650-950°C. At more high temperatures an exit of by-products of methane and carbon considerably increases. Addition of oxygen both in methane gas mixture and in ethane one, leads to decrease of selectivity of main C2 hydrocarbons due to formation of a by-product CO.
Cite: Sigaeva S.S. , Anoshkina E.A. , Temerev V.L. , Shlyapin D.A.
Comparative Research of Pyrolysis of Light Alkanes (Methane and Ethane) on the Resistive FeCrAl Catalyst
AIP Conference Proceedings. 2019. V.2141. 020026 :1-6. DOI: 10.1063/1.5122045 WOS Scopus РИНЦ AN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Dates:
Published online: Aug 28, 2019
Identifiers:
Web of science: WOS:000516716100026
Scopus: 2-s2.0-85072128141
Elibrary: 41674815
Chemical Abstracts: 2019:2098913
OpenAlex: W2970529693
publication_identifier.sciact_ihcp_identifier_type: 1953
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