Stability of PdO-Re2O7/SO42-/ZrO2-Al2O3 Catalyst for Direct Synthesis of Propylene From Ethylene Научная публикация
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Юбилейная научная конференция "XXI век: Химия в жизнь" 24-26 апр. 2019 , Омск |
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| Журнал |
AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616 |
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| Вых. Данные | Год: 2019, Том: 2143, Номер статьи : 020011, Страниц : 9 DOI: 10.1063/1.5122910 | ||
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| Организации |
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Информация о финансировании (1)
| 1 | Федеральное агентство научных организаций России | V.46.2.5. (АААА-А17-117021450096-8) |
Реферат:
During tests of palladium-rhenium catalysts based on sulfated zirconia in the process of direct synthesis of propylene from ethylene, it was found out that modifying the support with γ-Al2O3 increases significantly the stability of the system. Multi-cycle tests showed that systems with alumina content of 20 and 40 wt. % maintain its activity during a few tens of hours at the level of 50-80 %. The propylene yield from cycle to cycle remains practically unchanged (28-35 wt. %). According to UV spectroscopy and GLC with MSD, changes in the palladium and rhenium valence state don’t occur during the catalysts operation. The catalyst deactivation is caused by the C8+ oligomers deposit on its surface resulting from secondary processes of butenes oligomerization on the catalyst acid sites and C6+ hydrocarbons metathesis.
Библиографическая ссылка:
Sayfulina L.F.
, Buluchevskiy E.A.
, Lavrenov A.V.
, Arbuzov A.B.
, Karpova T.R.
Stability of PdO-Re2O7/SO42-/ZrO2-Al2O3 Catalyst for Direct Synthesis of Propylene From Ethylene
AIP Conference Proceedings. 2019. V.2143. 020011 :1-9. DOI: 10.1063/1.5122910 WOS Scopus РИНЦ CAPlus OpenAlex ЦНХТ ID
Stability of PdO-Re2O7/SO42-/ZrO2-Al2O3 Catalyst for Direct Synthesis of Propylene From Ethylene
AIP Conference Proceedings. 2019. V.2143. 020011 :1-9. DOI: 10.1063/1.5122910 WOS Scopus РИНЦ CAPlus OpenAlex ЦНХТ ID
Даты:
| Опубликована online: | 16 авг. 2019 г. |
Идентификаторы БД:
| Web of science: | WOS:000505769900011 |
| Scopus: | 2-s2.0-85071272573 |
| РИНЦ: | 41659360 |
| Chemical Abstracts: | 2019:2069959 |
| OpenAlex: | W2969020061 |
| ЦНХТ ID: | 2050 |