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Kinetics and Composition of Gaseous Products of Pyrolysis of Organometallic Complexes of Nickel, Iron, and Copper with Inorganic Anions Full article

Journal Combustion, Explosion, and Shock Waves
ISSN: 0010-5082 , E-ISSN: 1573-8345
Output data Year: 2024, Volume: 60, Number: 1, Pages: 25-41 Pages count : 17 DOI: 10.1134/s0010508224010040
Tags organometallic complexes, imidazole, iron oxide, nickel oxide, copper oxide, thermal decomposition kinetics, nanoscale materials
Authors Shmakov A.G. 1 , Paletsky A.A. 1 , Netskina O.V. 2 , Dmitruk K.A. 2,3 , Komova O.V. 2 , Mukha S.A. 2
Affiliations
1 Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
3 Novosibirsk State University, Novosibirsk, 630090 Russia

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation 075-15-2020-781

Abstract: Organometallic complexes of transition metals with inorganic anions are considered as promising precursors for the synthesis of nanoscale materials used in various applications including chemical catalysis. In this work, organometallic complexes of nickel, iron, and copper with imidazole as an organic ligand and the nitrate anion as an inorganic ligand were synthesized and characterized. The kinetic parameters of thermal decomposition of the synthesized organometallic complexes were determined by low heating-rate thermogravimetric analysis and high-speed dynamic mass spectrometric thermal analysis. The main gaseous products of thermal decomposition of the complexes under high-speed heating were identified. The chemical and phase compositions of condensed combustion products of the organometallic complexes in air were studied.
Cite: Shmakov A.G. , Paletsky A.A. , Netskina O.V. , Dmitruk K.A. , Komova O.V. , Mukha S.A.
Kinetics and Composition of Gaseous Products of Pyrolysis of Organometallic Complexes of Nickel, Iron, and Copper with Inorganic Anions
Combustion, Explosion, and Shock Waves. 2024. V.60. N1. P.25-41. DOI: 10.1134/s0010508224010040 WOS Scopus РИНЦ OpenAlex
Original: Шмаков А.Г. , Палецкий А.А. , Нецкина О.В. , Дмитрук К.А. , Комова О.В. , Муха С.А.
Кинетика и состав газообразных продуктов пиролиза металлорганических комплексов никеля, железа и меди с неорганическими анионами
Физика горения и взрыва. 2024. №1. С.29-47. DOI: 10.15372/fgv2022.9251 РИНЦ OpenAlex
Dates:
Submitted: Nov 9, 2022
Accepted: Dec 14, 2022
Published print: Jan 1, 2024
Published online: Apr 22, 2024
Identifiers:
Web of science: WOS:001206349000012
Scopus: 2-s2.0-85191072987
Elibrary: 67304978
OpenAlex: W4395015813
Citing: Пока нет цитирований
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