Preparation of the Ferrous Complex with Cysteine and Its Transformations Full article
| Journal |
Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350 |
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| Output data | Year: 2024, Volume: 94, Number: 6, Pages: 1297-1308 Pages count : 12 DOI: 10.1134/S1070363224060082 | ||||
| Tags | ferrous cysteinate,x-ray photoelectron spectroscopy,transformation | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Ministry of Science and Higher Education of the Russian Federation | FWUZ-2021-0005 (121031700313-8) |
| 2 | The Ministry of Education and Science of the Russian Federation | FWUZ-2021-0002 (121031700315-2) |
Abstract:
Ferrous cysteinate nanoparticles in the form of hexagonal nanoplates up to 20 nm thick have been synthesized in aerobic conditions. Their size has been confirmed by scanning electron microscopy. Their composition, investigated using atomic emission spectroscopy with inductively coupled plasma (ICP-AES), CHNS analysis, and IR spectroscopy, has coincided with the known complex Na2Fe(cyst)2·H2O (cyst being the cysteine fragment –SCH2СН(NН2)СОО–). Using X-ray photoelectron spectroscopy (XPS) and powder X-ray diffraction (XRD), the chemical transformations of the compound obtained under the action of air oxygen and moisture have been studied. Under these conditions, the Fe2+(cyst)(H2O)1.5 complex has been formed.
Cite:
Koshcheeva O.S.
, Koscheev S.V.
, Skiba T.V.
, Korolkov I.V.
, Maksimovskiy E.A.
, Kolodin A.N.
, Zubareva A.P.
Preparation of the Ferrous Complex with Cysteine and Its Transformations
Russian Journal of General Chemistry. 2024. V.94. N6. P.1297-1308. DOI: 10.1134/S1070363224060082 WOS Scopus РИНЦ OpenAlex
Preparation of the Ferrous Complex with Cysteine and Its Transformations
Russian Journal of General Chemistry. 2024. V.94. N6. P.1297-1308. DOI: 10.1134/S1070363224060082 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Jun 1, 2024 |
| Submitted: | Jun 4, 2024 |
| Accepted: | Jun 28, 2024 |
| Published online: | Aug 16, 2024 |
Identifiers:
| Web of science: | WOS:001297240100029 |
| Scopus: | 2-s2.0-85201425209 |
| Elibrary: | 68612332 |
| OpenAlex: | W4401636436 |