Statistical Modeling of Solution Combustion Synthesis for Ni/A2O3 Catalyst in Methane Decomposition to Hydrogen and Carbon Nanofibers | Sciact - CRIS-system of Boreskov Institute of Catalysis

Statistical Modeling of Solution Combustion Synthesis for Ni/A2O3 Catalyst in Methane Decomposition to Hydrogen and Carbon Nanofibers Full article

Journal

International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487

Output data

Year: 2024, Volume: 89, Pages: 1342-1353 Pages count : 12 DOI: 10.1016/j.ijhydene.2024.09.254

Tags

Hydrogen; Catalyst; Methane decomposition; Carbon nanofibers; Solution combustion synthesis; Citric acid

Authors

Kurmashov Pavel B. ¹ , Timofeev Vladimir S. ¹ , Ukhina Arina V. ² , Ishchenko Arcady V. ³ , Larina Tatyana V. ³ , Chesalov Yurii A. ³ , Tan Licheng ⁴ , Chen Yiwang ^4,5 , Maksimovskiy Evgeny A. ⁶ , Bannov Alexander G. ¹

Affiliations

1	Novosibirsk State Technical University, Novosibirsk, 630087, K. Marx Ave. 20, Russia
2	Institute of Solid State Chemistry and Mechanochemistry SB RAS, Novosibirsk, 630128, Kutateladze Str. 18, Russia
3	Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090, Akademika Lavrent'yeva Ave. 5, Russia
4	College of Chemistry and Chemical Engineering/Institute of Polymers and Energy Chemistry (IPEC), Nanchang University, 999 Xuefu Avenue, Nanchang, 330031, China
5	Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Jiangxi Normal University, 99 Ziyang Avenue, Nanchang, 330022, China
6	Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, 630090, Akademika Lavrent'eva 3, Russia

Funding (2)

1	Ministry of Science and Higher Education of the Russian Federation	075-12-2021-697
2	Russian Science Foundation	24-29-00661 (124021900114-7)

This paper is focused on the solution combustion synthesis (SCS) of a set of 90Ni/10Al2O3 (wt. %) catalysts for the production of hydrogen and carbon nanofibers through methane decomposition. A novel approach was employed to optimize the SCS of the catalysts in order to enhance the yields of hydrogen. The obtained catalysts were tested in methane decomposition at 550 °C and 1 bar. Transmission electron microscopy, energy-dispersive X-ray spectroscopy, low temperature nitrogen adsorption, and X-ray diffraction were utilized to investigate the catalysts. The SCS process involved programmable heating of a mixture of Ni(NO3)2·6H2O and Al(NO3)3·9H2O with citric acid (C6H8O7) from room temperature to 350–450 °C at a heating rates 1–10 °C/min and exposure durations of 0–20 min. It was discovered that a high specific yield of hydrogen (17.1 mol/gcat.) and carbon nanofibers (171 g/gcat.) can be achieved by synthesizing at 450 °C using a heating rate of 1 °C/min without additional exposure.

Kurmashov P.B. , Timofeev V.S. , Ukhina A.V. , Ishchenko A.V. , Larina T.V. , Chesalov Y.A. , Tan L. , Chen Y. , Maksimovskiy E.A. , Bannov A.G.
Statistical Modeling of Solution Combustion Synthesis for Ni/A2O3 Catalyst in Methane Decomposition to Hydrogen and Carbon Nanofibers
International Journal of Hydrogen Energy. 2024. V.89. P.1342-1353. DOI: 10.1016/j.ijhydene.2024.09.254 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Mar 15, 2024
Accepted:	Sep 18, 2024
Published online:	Oct 4, 2024
Published print:	Nov 4, 2024

Web of science:	WOS:001333323800001
Scopus:	2-s2.0-85205438133
Elibrary:	73951624
Chemical Abstracts:	2024:2147963
OpenAlex:	W4403130615

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Scopus	1
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