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Single-Atom Catalysts Supported on Covalent Triazine Frameworks Full article

Journal Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875
Output data Year: 2025, Volume: 690, Article number : 120035, Pages count : 15 DOI: 10.1016/j.apcata.2024.120035
Tags Single-atom catalyst; Covalent triazine frameworks; Active site; Molecular structure; EXAFS
Authors Golub Fedor S. 1 , Xiang Quanjun 2 , Bulushev Dmitri A. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Pr. Lavrentieva 5, Novosibirsk 630090, Russia
2 State Key Laboratory of Electronic Thin Film and Integrated Devices, School of Electronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu 610054, PR China

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation FWUR-2024-0036

Abstract: Covalent triazine frameworks (CTFs) are relatively novel materials and could be used as supports for single-atom metal catalysts (SACs), which attract a lot of interest during last years. The present review shows that CTFs are suitable supports for SACs for different reactions including oxidation, hydroformylation, O2 reduction, N2 fixation, CO2 photoreduction, hydrogen production, transfer and evolution. It discusses synthesis techniques and focuses on the structure of the obtained single-atom active sites including Pd, Ir, Ru, Rh, Pt, Ni, Co, Cu, and Fe atoms. It also considers some mechanisms of the mentioned reactions. The critical challenges and future perspectives for SACs based on CTFs are considered. This knowledge could be used as a base for design and engineering of single-atom active sites and will allow one to develop novel catalysts for different catalytic processes.
Cite: Golub F.S. , Xiang Q. , Bulushev D.A.
Single-Atom Catalysts Supported on Covalent Triazine Frameworks
Applied Catalysis A: General. 2025. V.690. 120035 :1-15. DOI: 10.1016/j.apcata.2024.120035 WOS Scopus AN OpenAlex
Dates:
Submitted: Sep 11, 2024
Accepted: Nov 25, 2024
Published online: Nov 26, 2024
Published print: Jan 25, 2025
Identifiers:
Web of science: WOS:001373085100001
Scopus: 2-s2.0-85210067616
Chemical Abstracts: 2024:2614595
OpenAlex: W4404734491
Citing: Пока нет цитирований
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