Thermolysis of Copper(II) Salts of Maleic Acid. Synthesis of Metal-Polymer Composites | Sciact - CRIS-система Института катализа

Thermolysis of Copper(II) Salts of Maleic Acid. Synthesis of Metal-Polymer Composites Научная публикация

Журнал

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Вых. Данные

Год: 2013, Том: 39, Номер: 5, Страницы: 415-420 Страниц : 6 DOI: 10.1134/S1070328413050102

Ключевые слова

Fumarate; Maleic Acid; Thermolysis; Maleic Anhydride; Maleate Decomposition

Авторы

Yudanova L.I. ¹ , Logvinenko V.A. ¹ , Yudanov N.F. ¹ , Rudina N.A. ² , Ishchenko A.V. ² , Semyannikov P.P. ¹ , Sheludyakova L.A. ¹ , Alferova N.I. ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia
2	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

The thermal decomposition of neutral ([Cu(H2O)(C4H2O4)]) and acidic ([Cu(H2O)4](C4H3O4)2) maleates can conventionally be divided into four stages: (1) dehydration, (2) polymerization, (3) isomerization of the maleate ion to the trans form with the simultaneous reduction Cu(II) → Cu(I), and (4) decarboxylation of copper(I) fumarate. The third and fourth stages of the decomposition of these salts coincide. The residue after the thermolysis of copper(II) maleates in a He flow is a composite consisting of aggregates from 50 nm to several microns in size. Spherical conglomerates (50–200 nm) containing many spherical Cu particles (5–10 nm) are incorporated into the organic polymer matrix of these aggregates.

Yudanova L.I. , Logvinenko V.A. , Yudanov N.F. , Rudina N.A. , Ishchenko A.V. , Semyannikov P.P. , Sheludyakova L.A. , Alferova N.I.
Thermolysis of Copper(II) Salts of Maleic Acid. Synthesis of Metal-Polymer Composites
Russian Journal of Coordination Chemistry. 2013. V.39. N5. P.415-420. DOI: 10.1134/S1070328413050102 WOS Scopus РИНЦ CAPlusCA OpenAlex

Юданова Л.И. , Логвиненко В.А. , Юданов Н.Ф. , Рудина Н.А. , Ищенко А.В. , Семянников П.П. , Шелудякова Л.А. , Алферова Н.И.
Термолиз солей малеиновой кислоты Cu(II). Синтез композитов металл-полимер
Координационная химия. 2013. Т.39. №5. С.309-314. DOI: 10.7868/S0132344X13050101 РИНЦ OpenAlex

Поступила в редакцию:	31 авг. 2012 г.
Опубликована в печати:	1 мая 2013 г.
Опубликована online:	9 мая 2013 г.

Web of science:	WOS:000318573600009
Scopus:	2-s2.0-84877727098
РИНЦ:	20428118
Chemical Abstracts:	2013:708342
Chemical Abstracts (print):	159:380652
OpenAlex:	W2048850884

БД	Цитирований
Web of science	10
Scopus	11
РИНЦ	9
OpenAlex	13