Validation of a Kinetic Model for Methanation of COx Gases with Literature Data Научная публикация
| Журнал |
Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045 |
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| Вых. Данные | Год: 2025, Том: 64, Номер: 3, Страницы: 1518–1527 Страниц : 10 DOI: 10.1021/acs.iecr.4c04070 | ||||||||
| Ключевые слова | Kinetic theory of gases; Methanation; Reaction rates; Sensitivity analysis | ||||||||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | National Council of Science and Technology | |
| 2 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | FEWZ-2024-0015 |
Реферат:
A kinetic modeling study was performed for the methanation of COx gases using experimental data from the literature. The original kinetic parameters were used to calculate the different reaction rates, which resulted in an average absolute error of 11%. By means of a sensitivity analysis, it was demonstrated that the reported values of parameters do not correspond to the global minimum of the objective function. A recalculation of the kinetic parameters using an optimization methodology was performed in order to obtain the optimal values of the parameters. After applying the methodology, a series of simulations using the optimized values was performed where the predictions obtained with the new values of parameters exhibited a better accuracy to predict the experimental data in comparison with the reported kinetic parameter values with an average absolute error of 2.18%.
Библиографическая ссылка:
Ríos J.J.
, Ancheyta J.
, Elyshev A.
, Zagoruiko A.
Validation of a Kinetic Model for Methanation of COx Gases with Literature Data
Industrial and Engineering Chemistry Research. 2025. V.64. N3. P.1518–1527. DOI: 10.1021/acs.iecr.4c04070 WOS Scopus РИНЦ OpenAlex CAPlusCA
Validation of a Kinetic Model for Methanation of COx Gases with Literature Data
Industrial and Engineering Chemistry Research. 2025. V.64. N3. P.1518–1527. DOI: 10.1021/acs.iecr.4c04070 WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Поступила в редакцию: | 25 окт. 2024 г. |
| Принята к публикации: | 6 янв. 2025 г. |
| Опубликована в печати: | 10 янв. 2025 г. |
| Опубликована online: | 10 янв. 2025 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:001396732500001 |
| ≡ Scopus: | 2-s2.0-85214579857 |
| ≡ РИНЦ: | 81196967 |
| ≡ OpenAlex: | W4406275998 |
| ≡ Chemical Abstracts: | 2025:100781 |
| ≡ Chemical Abstracts (print): | 189:286021 |