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Control of Structural-Mechanical Properties of Pseudoboehmite Pastes by Changing the Plasticizing Agent Научная публикация

Журнал Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296
Вых. Данные Год: 2024, Том: 97, Номер: 8, Страницы: 655-666 Страниц : 12 DOI: 10.1134/s1070427224080044
Ключевые слова plasticization, pseudoboehmite structural-mechanical properties, extrusion, alumina
Авторы Mukhacheva P.P. 1 , Kruglyakov V.Yu. 1 , Vatutina Yu.V. 1 , Nadeina K.A. 1 , Ruvinskiy P.S. 1 , Dubinin Yu.V. 1 , Klimov O.V. 1 , Noskov A.S. 1
Организации
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090 Russia

Информация о финансировании (1)

1 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) FWUR-2024-0037

Реферат: The study of the influence the type of plasticizing organic/inorganic agents on structural-mechanical properties (plastic strength, molding pressure, limit shear stress, greatest plastic viscosity, plasticity and etc.) of the pseudoboehmite pastes is presented. Samples of the pastes were prepared using plasticizing agents of organic nature (acetic, malic, tartaric, oxalic and citric acids and diethyelen glycol) and inorganic nature such as nitric and phosphoric acids, aqueous ammonia solution and ammonium hydrocarbonate. Our results suggest the pastes plasticized with nitric/phosphoric acids or with diethylene glycol demonstrate the highest plastic strength in the set. Plastic strength values were found to correlate well with the molding pressure necessary for the paste shaping through a piston extruder. The structural-mechanical type of paste was determined using a modulus of elasticity, viscosity and limit shear stress. All pastes were found to be suitable for extrusion molding and did not belong to SMT types 0 and III. The plasticizing agent was found to affect SMT type of paste. Paste types I, II, IV, and V were obtained by changing the plasticizing agent. Alumina granules without visible defects and with sufficient crush strength value were prepared using the investigated pastes. This allows them to be used as supports/adsorbents/catalysts for industrial processes.
Библиографическая ссылка: Mukhacheva P.P. , Kruglyakov V.Y. , Vatutina Y.V. , Nadeina K.A. , Ruvinskiy P.S. , Dubinin Y.V. , Klimov O.V. , Noskov A.S.
Control of Structural-Mechanical Properties of Pseudoboehmite Pastes by Changing the Plasticizing Agent
Russian Journal of Applied Chemistry. 2024. V.97. N8. P.655-666. DOI: 10.1134/s1070427224080044 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Опубликована в печати: 1 авг. 2024 г.
Поступила в редакцию: 9 окт. 2024 г.
Принята к публикации: 15 янв. 2025 г.
Опубликована online: 17 февр. 2025 г.
Идентификаторы БД:
Web of science: WOS:001424298000003
Scopus: 2-s2.0-85219755177
РИНЦ: 80348811
Chemical Abstracts: 2025:410768
OpenAlex: W4407632049
Цитирование в БД: Пока нет цитирований
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