Sustainable Synthesis of Composite Ceramics Using in situ Synchrotron X-ray Diffraction for Effective Immobilization of Sr-90 and Its Fission Products | Sciact - CRIS-система Института катализа

Sustainable Synthesis of Composite Ceramics Using in situ Synchrotron X-ray Diffraction for Effective Immobilization of Sr-90 and Its Fission Products Научная публикация

Журнал

Journal of Radioanalytical and Nuclear Chemistry
ISSN: 0236-5731 , E-ISSN: 1588-2780

Вых. Данные

Год: 2025, Том: 334, Страницы: 2103–2120 Страниц : 18 DOI: 10.1007/s10967-024-09954-0

Ключевые слова

Ceramics; Mineral-like ceramics; Radionuclides; Immobilization; Strontium-90; Yttrium-90; Zirconium-90; Radioactive waste;Reactive spark plasma sintering (SPS-RS); Hydrolytic stability

Авторы

Papynov E.K. ¹ , Belov A.A. ¹ , Shichalin O.O. ¹ , Zavjalov A.P. ² , Buravlev I.Yu. ¹ , Drankov A.N. ¹ , Azon S.A. ¹ , Fedorets A.N. ¹ , Buravleva A.A. ¹ , Yarusova S.B. ³ , Mayorov V.Yu. ⁴ , Kondrikov N.B. ¹ , Tananaev I.G. ⁵ , Sergienko V.I. ⁶

Организации

1	Far Eastern Federal University, 10 Ajax Bay, Russky Island, Vladivostok, Russia, 690922
2	Synchrotron Research Department, Synchrotron Radiation Facility SKIF, Boreskov Institute of Catalysis Siberian Branch Russian Academy of Sciences, 1, Pr. Nikolsky, R.P. Koltsovo, Novosibirsk Region, Russian Federation, 630559
3	Vladivostok State University, Gogolya, 41, Vladivostok, Russian Federation, 690014
4	Far Eastern Geological Institute, Russian Academy of Sciences, 100 Let Vladivostok Avenue 159, Vladivostok, Russian Federation, 690000
5	Kola Science Center, Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Russian Academy of Sciences, Akademgorodok, 26a, Apatity, Russian Federation, 184209
6	Presidium of the Far Eastern Branch of the Russian Academy of Sciences, Svetlanskaya, 50, Vladivostok, Russian Federation, 690000

In this work the method of obtaining composite ceramics based on perovskite and pyrochlore of compositions YxZrxSr1-3xTiO3 (x = 0.1, x = 0.2, x = 0.3) and Y2(ZrxTi)2O7 (x = 1) using the technology of reactive spark plasma sintering has been investigated. A comprehensive study of phase transformations, structure formation and physical and mechanical characteristics of ceramics depending on the ratio of Sr2+/Y3+/Zr4+ has been carried out by XRD, SEM, EDS and “diffraction movie” methods at the synchrotron radiation source. High hydrolytic stability of ceramics is proved and the mechanism of low leaching rate of Sr2+ < 10–7 g cm−2 day, Y3+ and Zr4+ < 10–5 g cm−2 day is described, which corresponds to GOST R 50926-96 and ANSI/ANS 16.1. The results of the work are promising for conditioning of radioactive waste and production of radioisotope products.

Papynov E.K. , Belov A.A. , Shichalin O.O. , Zavjalov A.P. , Buravlev I.Y. , Drankov A.N. , Azon S.A. , Fedorets A.N. , Buravleva A.A. , Yarusova S.B. , Mayorov V.Y. , Kondrikov N.B. , Tananaev I.G. , Sergienko V.I.
Sustainable Synthesis of Composite Ceramics Using in situ Synchrotron X-ray Diffraction for Effective Immobilization of Sr-90 and Its Fission Products
Journal of Radioanalytical and Nuclear Chemistry. 2025. V.334. P.2103–2120. DOI: 10.1007/s10967-024-09954-0 WOS Scopus РИНЦ OpenAlex СКИФ ID

Поступила в редакцию:	8 окт. 2024 г.
Принята к публикации:	20 дек. 2024 г.
Опубликована online:	31 дек. 2024 г.
Опубликована в печати:	1 мар. 2025 г.

Web of science:	WOS:001387777900001
Scopus:	2-s2.0-85213710174
РИНЦ:	80200910
OpenAlex:	W4405949454
СКИФ ID:	3700

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