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Effect of ZSM-5 Zeolite Modification by Iron Cations on the Direction of n-Dodecane Transformations in the Presence of 2-Methylthiophene Научная публикация

Журнал Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296
Вых. Данные Год: 2025, Том: 98, Номер: 5, Страницы: 248–256 Страниц : 9 DOI: 10.1134/S1070427225050040
Ключевые слова catalytic cracking, iron, zeolite, ZSM-5
Авторы Izoitko A.I. 1 , Gilyazutdinova A.S. 1 , Koveza V.A. 1 , Potapenko O.V. 1
Организации
1 Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, Omsk, 644040 Russia

Информация о финансировании (1)

1 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) FWUR-2024-0039

Реферат: The eff ect of integration iron cations into zeolite ZSM-5 on the physicochemical properties of the material and the direction of transformation of n-dodecane and 2-methylthiophenes (5000 ppm S) in catalytic cracking was investigated. The integration of iron led to a signifi cant increase in the total acidity of zeolites with SiO2/Al2O3 ratios of 23 and a slight increase for zeolites with SiO2/Al2O3 ratios of 80. For both types, the volume of micropore remained unchanged. It was found that modifying zeolite ZSM-5 with SiO2/Al2O3 ratios of 23 with iron increased the yield of aromatic compounds from 27.1 to 38.1 wt %, and light olefi ns from 22.5 to 30.3%. The content of sulfur compounds decreases by 44% with an increase in the proportion of iron oxide in zeolite ZSM-5 with SiO2/Al2O3 ratios of 23.
Библиографическая ссылка: Izoitko A.I. , Gilyazutdinova A.S. , Koveza V.A. , Potapenko O.V.
Effect of ZSM-5 Zeolite Modification by Iron Cations on the Direction of n-Dodecane Transformations in the Presence of 2-Methylthiophene
Russian Journal of Applied Chemistry. 2025. V.98. N5. P.248–256. DOI: 10.1134/S1070427225050040 ЦНХТ ID
Даты:
Поступила в редакцию: 27 янв. 2025 г.
Принята к публикации: 19 сент. 2025 г.
Идентификаторы БД:
ЦНХТ ID: 4500
Цитирование в БД: Пока нет цитирований
Альметрики: