Modification of Carbon Black for Application in Metal-Ion Batteries. I. The Influence of Heat Treatment on the Structure of Carbon Black | Sciact - CRIS-system of Boreskov Institute of Catalysis

Modification of Carbon Black for Application in Metal-Ion Batteries. I. The Influence of Heat Treatment on the Structure of Carbon Black Full article

Journal

Protection of Metals and Physical Chemistry of Surfaces
ISSN: 2070-2051 , E-ISSN: 2070-206X

Output data

Year: 2025, Volume: 61, Number: 2, Pages: 257-269 Pages count : 13 DOI: 10.1134/S2070205124702368

Authors

Knyazheva O.A. ¹ , Lavrenov A.V. ¹ , Potapenko O.V. ¹ , Kokhanovskaya O.A. ¹ , Baklanova O.N. ¹ , Trenikhin M.V. ¹ , Yurpalov V.L. ¹ , Arbuzov A.B. ¹ , Gorbunova O.V. ¹ , Muromtsev I.V. ¹ , Malinovsky Yu.G. ¹

Affiliations

1	Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Omsk, 644040 Russia

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

FWUR-2024-0039

The influence of heat treatment in carbon dioxide atmosphere (900°C) and low-temperature graphitization (1500°C) on the transformation of primary particles in N375 carbon black was studied. According to TEM, the outer layer of primary particles increases in the length of the graphene layers from 0.96 to 1.28 nm under the influence of carbon dioxide treatment. The carbon in the inner part of the particles is intensively oxidized, which leads to the formation of micropores and an increase in the specific surface area of the material by almost 11 times. Further low-temperature graphitization of oxidized carbon black leads to the formation of polyhedral particles in its structure, consisting of extended graphite-like nanocrystalliteswith an interlayer distance d002 of 0.37—0.38 nm. The specific surface area of the obtained carbon black samples reached 216 m2 /g, which is 2.5 times more than that for the original N375.

Knyazheva O.A. , Lavrenov A.V. , Potapenko O.V. , Kokhanovskaya O.A. , Baklanova O.N. , Trenikhin M.V. , Yurpalov V.L. , Arbuzov A.B. , Gorbunova O.V. , Muromtsev I.V. , Malinovsky Y.G.
Modification of Carbon Black for Application in Metal-Ion Batteries. I. The Influence of Heat Treatment on the Structure of Carbon Black
Protection of Metals and Physical Chemistry of Surfaces. 2025. V.61. N2. P.257-269. DOI: 10.1134/S2070205124702368

Княжева О.А. , Лавренов А.В. , Потапенко О.В. , Кохановская О.А. , Бакланова О.Н. , Тренихин М.В. , Юрпалов В.Л. , Арбузов А.Б. , Горбунова О.В. , Муромцев И.В. , Малиновский Ю.Г.
Модифицирование технического углерода для применения в автономных источниках тока. I. Влияние термической обработки на структуру технического углерода
Физикохимия поверхности и защита материалов. 2024. Т.60. №6. С.605-618. DOI: 10.31857/S0044185624060045 РИНЦ publication_identifier_short.sciact_ihcp_identifier_type

Submitted:	Jun 6, 2024
Accepted:	Oct 10, 2024
Published print:	Apr 1, 2025
Published online:	Sep 26, 2025

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