Sciact
  • EN
  • RU

Hydrogen Transfer Reactions in the Presence of (Ni, Co)Mo-Sulfide Catalysts as an Effective Tool for Hydrodechlorination: The Role of the Nature of Lower Alcohols Full article

Journal New Journal of Chemistry
ISSN: 1144-0546 , E-ISSN: 1369-9261
Output data Year: 2026, Volume: 50, Number: 2, Pages: 676-685 Pages count : 10 DOI: 10.1039/d5nj03435c
Authors Romanov Alexander 1 , Nesterov Nikolai 1 , Pakharukova Vera 1 , Prosvirin Igor 1 , Salomatina Anna 1 , Klimov Oleg 1 , Martyanov Oleg 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Academician Lavrentiev ave. 5, Novosibirsk 630090, Russia

Abstract: The influence of the nature of alcohols (MeOH, EtOH, 1-PrOH, 2-PrOH, 2-BuOH, and CyOH) on the process of hydrodechlorination of chlorobenzene (PhCl) under conditions of hydrogen transfer in the presence of (Ni, Co)Mo sulfide catalysts was investigated. It was found that the efficiency of chlorine removal depends on the nature of the alcohol: 2-PrOH > 2-BuOH > MeOH > CyOH > 1-PrOH > EtOH. Minor products (alkylbenzenes) were observed only for secondary alcohols such as 2-PrOH, 2-BuOH, and CyOH. The results demonstrate the potential of alcohols (2-PrOH, 2-BuOH, CyOH, and MeOH) as alternative hydrogen donors for the environmentally safe processing of organochlorine waste.
Cite: Romanov A. , Nesterov N. , Pakharukova V. , Prosvirin I. , Salomatina A. , Klimov O. , Martyanov O.
Hydrogen Transfer Reactions in the Presence of (Ni, Co)Mo-Sulfide Catalysts as an Effective Tool for Hydrodechlorination: The Role of the Nature of Lower Alcohols
New Journal of Chemistry. 2026. V.50. N2. P.676-685. DOI: 10.1039/d5nj03435c WOS Scopus AN OpenAlex
Dates:
Submitted: Aug 26, 2025
Accepted: Nov 26, 2025
Published online: Dec 12, 2025
Published print: Jan 12, 2026
Identifiers:
Web of science: WOS:001637872100001
Scopus: 2-s2.0-105024781757
Chemical Abstracts: 2025:3068711
OpenAlex: W7114912145
Citing:
DB Citing
OpenAlex Нет цитирований
Scopus Нет цитирований
Altmetrics: