Tandem Rh-based Structured Reformer and Ni-YSZ SOFC for Decentralized Gasoline-to-power Conversion | Sciact - CRIS-система Института катализа

Tandem Rh-based Structured Reformer and Ni-YSZ SOFC for Decentralized Gasoline-to-power Conversion Научная публикация

Журнал

Fuel
ISSN: 0016-2361 , E-ISSN: 1873-7153

Вых. Данные

Год: 2026, Том: 413, Номер статьи : 138249, Страниц : 10 DOI: 10.1016/j.fuel.2026.138249

Ключевые слова

Autothermal reforming; Gasoline; Syngas; SOFC feeding; On-board fuel processing

Авторы

Ruban N.V. ^1,2 , Rogozhnikov V.N. ² , Svintsitskiy D.A. ² , Pakharukova V.P. ² , Snytnikov P.V. ² , Thybaut J.W. ¹ , Potemkin D.I. ²

Организации

1	Ghent University, Laboratory for Chemical Technology, Technologiepark 125, 9052 Ghent, Belgium
2	Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva, 5, Novosibirsk 630090, Russia

Информация о финансировании (1)

Российский научный фонд

24-73-10134

This work reports on the performance of a 0.24 wt% Rh/Ce0.75Zr0.25O2–δ–η-Al2O3/FeCrAl structured catalyst in the autothermal reforming of commercial gasoline with a research octane number of 92. Stable syngas production amounting to 70 Nl·h−1 containing of 33.8 vol% H2 and 9.8 vol% CO was demonstrated over 50 h of continuous operation. The origin of the high catalytic efficiency was elucidated by physicochemical characterization (XPS, STEM, XRD), which confirmed the role of Rh redox flexibility (Rh3+ ⇄ Rh⁰) and Ce4+ ⇄ Ce3+ cycling in suppressing carbon formation and maintaining active site dispersion. The compatibility of the produced syngas with Ni–YSZ solid oxide fuel cells was assessed, and a reformer–SOFC tandem concept was proposed to supply 50 W to telecommunication equipment, with operational parameters derived from the present reformer performance. Such a system highlights the potential of integrating catalytic reforming with SOFC conversion for decentralized power generation in remote applications where access to centralized infrastructure is limited.

Ruban N.V. , Rogozhnikov V.N. , Svintsitskiy D.A. , Pakharukova V.P. , Snytnikov P.V. , Thybaut J.W. , Potemkin D.I.
Tandem Rh-based Structured Reformer and Ni-YSZ SOFC for Decentralized Gasoline-to-power Conversion
Fuel. 2026. V.413. 138249 :1-10. DOI: 10.1016/j.fuel.2026.138249CAPlus OpenAlex

Поступила в редакцию:	10 окт. 2025 г.
Принята к публикации:	1 янв. 2026 г.
Опубликована online:	8 янв. 2026 г.
Опубликована в печати:	1 июн. 2026 г.

Chemical Abstracts:	2026:115306
OpenAlex:	W7118761121

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