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A Comprehensive Analysis of Reactor Modeling Studies for the Methanation of Carbon Oxides Review

Journal Processes
ISSN: 2227-9717
Output data Year: 2026, Volume: 14, Number: 4, Article number : 659, Pages count : 44 DOI: 10.3390/pr14040659
Tags reactor modeling; kinetic modeling; carbon oxides methanation; power-to-gas
Authors Ríos Juan José 1 , Ancheyta Jorge 2,3 , Mantilla Angeles 1 , Elyshev Andrey 3 , Zagoruiko Andrey 3
Affiliations
1 Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada, Unidad Legaria, Instituto Politécnico Nacional, Legaria 694, Col. Irrigación, Mexico City 11500, Mexico
2 Escuela Superior de Ingeniería Química e Industrias Extractivas, Instituto Politécnico Nacional, Unidad Profesional Adolfo López Mateos, Zacatenco, Mexico City 07738, Mexico
3 School of Natural Sciences, Tyumen State University, 625003 Tyumen, Russia

Funding (1)

1 Russian Science Foundation 22-73-10015

Abstract: This work presents a comprehensive analysis of reactor modeling studies for the methanation of COx, with the aim of identifying trends, evaluating modeling strategies, and suggesting a generalized modeling framework. The analysis spans a wide range of configurations, including packed/fixed-bed reactors (immobilized catalyst pellets/particles), fluidized-bed reactors, and structured catalyst reactors, as well as membrane and slurry/bubble-column configurations when applicable. This highlights the diversity of modeling approaches used, ranging from simple 1D pseudo-homogeneous models to complex 2D heterogeneous simulations. Emphasis is placed on the governing assumptions, dimensional formulations, transport phenomena, and kinetic models employed across studies. By systematically comparing these models, this work identifies the most critical modeling assumptions and parameters that govern the prediction reliability of reactor performance (e.g., conversion andtemperatureprofiles) andinformreactor design. Theproposedreactormodelintegrates insights from the literature, balancing model fidelity and computational feasibility, and serves as a foundational tool for future modeling efforts and industrial applications. This work contributes to the field by offering a unified perspective that links model complexity to physical realism, providing valuable guidance in the development of predictive tools for COx methanation systems.
Cite: Ríos J.J. , Ancheyta J. , Mantilla A. , Elyshev A. , Zagoruiko A.
A Comprehensive Analysis of Reactor Modeling Studies for the Methanation of Carbon Oxides
Processes. 2026. V.14. N4. 659 :1-44. DOI: 10.3390/pr14040659 OpenAlex
Dates:
Submitted: Jan 16, 2026
Accepted: Feb 11, 2026
Published online: Feb 14, 2026
Identifiers:
≡ OpenAlex: W7128923263
Citing:
≡ OpenAlex 0 Сбор данных от 22.02.2026
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