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Effect of Support Modifier on Pt/Al2O3 Catalytic Performance in Propane Dehydrogenation Full article

Journal Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532
Output data Year: 2025, Volume: 65, Number: 11, Pages: 1329-1338 Pages count : 10 DOI: 10.1134/s0965544125601115
Tags propane dehydrogenation, platinum catalysts, modified alumina, acid–base properties
Authors Stepanova L.N. 1 , Nepomnyashchii A.A. 1 , Mironenko R.M. 1 , Gorbunova O.V. 1 , Gulyaeva T.I. 1 , Muromtsev I.V. 1
Affiliations
1 Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, 644040, Omsk, Russia

Abstract: A series of platinum catalysts were synthesized using Al2O3 supports modified with Na+ and Mg2+ cations (2 wt %). The phase compositions, textural properties, acidity, and catalytic performance of these catalysts in the non-oxidative dehydrogenation of propane were characterized by X-ray diffraction (XRD), low-temperature nitrogen adsorption–desorption, and temperature-programmed desorption of ammonia (NH3-TPD) and carbon dioxide (CO2-TPD). The catalytic activity decreased in the order: 2Mg/Al2O3 > Al2O3 > 2Na/Al2O3. The study demonstrates a correlation between the acid–base properties of the catalyst supports and the propane conversion pathway during dehydrogenation
Cite: Stepanova L.N. , Nepomnyashchii A.A. , Mironenko R.M. , Gorbunova O.V. , Gulyaeva T.I. , Muromtsev I.V.
Effect of Support Modifier on Pt/Al2O3 Catalytic Performance in Propane Dehydrogenation
Petroleum Chemistry. 2025. V.65. N11. P.1329-1338. DOI: 10.1134/s0965544125601115 WOS Scopus publication_identifier_short.sciact_ihcp_identifier_type
Dates:
Submitted: Jun 23, 2025
Accepted: Oct 29, 2025
Identifiers:
≡ Web of science: WOS:001664020500001
≡ Scopus: 2-s2.0-105027856166
≡ publication_identifier.sciact_ihcp_identifier_type: 4535
Citing: Пока нет цитирований
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