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UV-LED TiO2 Photocatalytic Oxidation of Acetone Vapor: Effect of High Frequency Controlled Periodic Illumination Full article

Journal Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883
Output data Year: 2015, Volume: 163, Pages: 143-149 Pages count : 7 DOI: 10.1016/j.apcatb.2014.07.034
Tags Controlled periodic illumination, Photocatalysis, Reaction kinetics simulation, Titanium dioxide, UV LED
Authors Korovin E. 1,2,3 , Selishchev D. 1,2 , Besov A. 1,2 , Kozlov D. 1,2,3
Affiliations
1 Novosibirsk State University, Novosibirsk, 630090, Russia
2 Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia
3 Research and Educational Centre for Energoefficient Catalysis (Novosibirsk State University), Novosibirsk, 630090, Russia

Funding (3)

1 Council for Grants of the President of the Russian Federation НШ-1183.2014.3
2 Federal Agency for Scientific Organizations V.44.2.11.
3 Novosibirsk National Research University

Abstract: We investigated the effect of controlled periodic illumination on quantum efficiency of acetone vapor photocatalytic oxidation. It was demonstrated that quantum efficiency increases with the increase of light pulses frequency and decrease of the duty cycle and at some point reaches its maximum value which is equal to the quantum efficiency obtained under the same average photon flux. Several kinetic models were applied to the experimental data. The general conclusion was made that there are only two kinetically distinguishable active species on TiO2 surface with the lifetimes in 10−3–101 s range.
Cite: Korovin E. , Selishchev D. , Besov A. , Kozlov D.
UV-LED TiO2 Photocatalytic Oxidation of Acetone Vapor: Effect of High Frequency Controlled Periodic Illumination
Applied Catalysis B: Environmental. 2015. V.163. P.143-149. DOI: 10.1016/j.apcatb.2014.07.034 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
Submitted: Apr 28, 2014
Accepted: Jul 15, 2014
Published online: Aug 4, 2014
Published print: Feb 1, 2015
Identifiers:
≡ Web of science: WOS:000343612500017
≡ Scopus: 2-s2.0-84906283505
≡ Elibrary: 23956516
≡ OpenAlex: W2091583623
≡ Chemical Abstracts: 2014:1328654
≡ Chemical Abstracts (print): 161:437899
Citing:
≡ Web of science 36 Сбор данных от 20.02.2026
≡ Scopus 36 Сбор данных от 22.02.2026
≡ Elibrary 36 Сбор данных от 22.02.2026
≡ OpenAlex 38 Сбор данных от 22.02.2026
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