Diesel Fuel Pre-Reforming into Methane-Hydrogen Mixtures | Sciact - CRIS-система Института катализа

Diesel Fuel Pre-Reforming into Methane-Hydrogen Mixtures Научная публикация

Журнал

Theoretical Foundations of Chemical Engineering
ISSN: 0040-5795 , E-ISSN: 1608-3431

Вых. Данные

Год: 2015, Том: 49, Номер: 1, Страницы: 30-40 Страниц : 11 DOI: 10.1134/S0040579515010030

Ключевые слова

adiabatic reactor, catalyst, diesel fuel, kinetics, methane-hydrogen mixture, pre-reforming

Авторы

Kirillov V.A. ^1,2,3 , Shigarov A.B. ^1,2,3 , Amosov Yu.I. ^1,2,3 , Belyaev V.D. ^1,2,3 , Urusov A.R. ⁴

Организации

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Lavrent’eva 5, Novosibirsk, 630090 Russia
2	OOO UNIKAT, pr. Lavrent’eva 5, Novosibirsk, 630090 Russia
3	Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090 Russia
4	Krylov State Research Centre, Moskovskoe sh. 44, St. Petersburg, 196158 Russia

Информация о финансировании (2)

1	Российский фонд фундаментальных исследований	13-03-12404
2	Министерство образования и науки Российской Федерации

The pre-reforming of diesel fuel combined with subsequent steam reforming of pre-reforming products integrated with membrane separation of hydrogen is the most promising way of obtaining pure hydrogen for fuel cells. Here, we consider the first part of this problem-diesel fuel pre-reforming. The following commercial nickel-containing catalysts have been tested in the pre-reforming reaction: NIAP-18 (Ni, 15 wt %; CaO, 8 wt %; Al2O3, 74.4 wt %), NIAP-12-05 (Ni, 48 wt %; Cr2O3, 27 wt %), NIAP-07-01 (NiO, 36 wt %), NIAP-07-05 (NiO, 38 wt %; Cr2O3, 12 wt %). A number of new pre-reforming catalysts based on manganese and cobalt compounds have also been examined. The tests have been carried out at pressures of 1, 6, and 15 atm, temperatures of 470–560°C, and gas hourly space velocities of 6000–12000 h−1. The experiments have demonstrated that the nickel-containing catalysts afford a near-equilibrium product composition, while the reaction over the catalysts based on manganese and cobalt compounds yields a nonequilibrium product composition. A mathematical model has been developed for diesel fuel pre-reforming in an adiabatic reactor with a fixed catalytic bed. Model parameters ranging from process kinetics to heat and mass transfer coefficients have been estimated. The results of modeling have been compared to experimental data available from the literature. The potential of the mathematical model has been illustrated by performing calculations for adiabatic reactors with various output capacities.

Kirillov V.A. , Shigarov A.B. , Amosov Y.I. , Belyaev V.D. , Urusov A.R.
Diesel Fuel Pre-Reforming into Methane-Hydrogen Mixtures
Theoretical Foundations of Chemical Engineering. 2015. V.49. N1. P.30-40. DOI: 10.1134/S0040579515010030 WOS Scopus РИНЦ CAPlusCA OpenAlex

Кириллов В.А. , Шигаров А.Б. , Амосов Ю.И. , Беляев В.Д. , Урусов А.Р.
Предриформинг дизельного топлива в метановодородные смеси
Теоретические основы химической технологии. 2015. Т.49. №1. С.32-43. DOI: 10.7868/S0040357115010030 РИНЦ OpenAlex

Поступила в редакцию:	11 авг. 2014 г.
Опубликована в печати:	1 янв. 2015 г.
Опубликована online:	16 февр. 2015 г.

Web of science:	WOS:000349372400004
Scopus:	2-s2.0-84923037977
РИНЦ:	24008630
Chemical Abstracts:	2015:280452
Chemical Abstracts (print):	164:24519
OpenAlex:	W2006976510

БД	Цитирований
Web of science	10
Scopus	11
РИНЦ	9
OpenAlex	10