Etanol Vapor Photocatalytic Oxidation with Uranyl Modified Titania Under Visible Light: Comparison with Silica and Alumina Full article
| Journal |
Journal of Photochemistry and Photobiology A: Chemistry
ISSN: 1010-6030 , E-ISSN: 1873-2666 |
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| Output data | Year: 2012, Volume: 250, Number: 1, Pages: 72-77 Pages count : 6 DOI: 10.1016/j.jphotochem.2012.09.015 | ||||
| Tags | Photocatalytic oxidation, Titanium dioxide, Uranyl nitrate, Visible light, Volatile organic compounds | ||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | The Ministry of Education and Science of the Russian Federation | 8440 |
| 2 | Siberian Branch of the Russian Academy of Sciences | 33 |
| 3 | Council for Grants of the President of the Russian Federation | НШ-524.2012.3 |
Abstract:
Gas-phase photocatalytic oxidation (PCO) of ethanol vapor in a batch reactor using UO2(NO3)2-modified titania, alumina and silica as photocatalysts was studied. The uranyl nitrate content was varied from 0.2 to 10 wt.%. Special optical glass filters were placed between the light source and reactor to cutoff the UV light. Photooxidation experiments under the visible light irradiation demonstrated that UO2(NO3)2 loading on TiO2 improves its activity in the ethanol photooxidation and CO2 formation. The influence of support and uranyl nitrate content on the ethanol vapor PCO was investigated. The rate of ethanol oxidation increased with the increase of uranyl content. Alumina and silica based photocatalysts demonstrated almost the same photoactivity whereas the titania based photocatalyst had at least a five times higher rate of the acetaldehyde accumulation. All the synthesized photocatalysts oxidize ethanol even under light with wavelength higher than 470 nm.
Cite:
Kolinko P.A.
, Filippov T.N.
, Kozlov D.V.
, Parmon V.N.
Etanol Vapor Photocatalytic Oxidation with Uranyl Modified Titania Under Visible Light: Comparison with Silica and Alumina
Journal of Photochemistry and Photobiology A: Chemistry. 2012. V.250. N1. P.72-77. DOI: 10.1016/j.jphotochem.2012.09.015 WOS Scopus РИНЦ OpenAlex ANCAN
Etanol Vapor Photocatalytic Oxidation with Uranyl Modified Titania Under Visible Light: Comparison with Silica and Alumina
Journal of Photochemistry and Photobiology A: Chemistry. 2012. V.250. N1. P.72-77. DOI: 10.1016/j.jphotochem.2012.09.015 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Aug 3, 2012 |
| Accepted: | Sep 29, 2012 |
| Published online: | Oct 9, 2012 |
| Published print: | Dec 15, 2012 |
Identifiers:
| ≡ Web of science: | WOS:000312524700010 |
| ≡ Scopus: | 2-s2.0-84868232071 |
| ≡ Elibrary: | 20498308 |
| ≡ OpenAlex: | W2058794469 |
| ≡ Chemical Abstracts: | 2012:1718377 |
| ≡ Chemical Abstracts (print): | 158:460679 |