Synthesis and X-Ray Structural Study of α-Thiopicolinanilidates of Copper and Nickel | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis and X-Ray Structural Study of α-Thiopicolinanilidates of Copper and Nickel Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 1971, Volume: 12, Number: 3, Pages: 435-438 Pages count : 4 DOI: 10.1007/BF00744631

Tags

Copper; Physical Chemistry; Nickel; Inorganic Chemistry; Structural Study

Authors

Plyasova L.M. ¹ , Ishhenko S.A. ¹ , Mamaeva E.K. ¹ , Rukhadze E.G. ¹ , Keier N.P. ¹ , Bystrenko T.N. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR

Copper (CuZ+), nickel, and cobalt thiopicolinanilidates, with the general formula M(TPA)2, were synthesized. It was found that Cu(TPA)z has one crystallographic modification (l), Ni(TPA)2 has two (II and II-A), and Co(TPA) 2 is x-ray amorphous. Single crystals of I and II were grown and studied by x-ray goniometric methods. The crystals belong to the monoclinic crystal system. The unit cell parameters are as follows: a = 5.84 .A, b = 22.5 A, c = 8,28 A, and β = 117o for Cu(TPA)2, and a= 5.48 A, b=17.44 A, c= 10.79 A, and β = 102 o for Ni(TPA)2, Z = 2, space group C2h(5) = P21/c. The structure of the chelate grouping Cu(2S, 2N) was determined, along with the positions of the molecules in the unit cell.

Plyasova L.M. , Ishhenko S.A. , Mamaeva E.K. , Rukhadze E.G. , Keier N.P. , Bystrenko T.N.
Synthesis and X-Ray Structural Study of α-Thiopicolinanilidates of Copper and Nickel
Journal of Structural Chemistry. 1971. V.12. N3. P.435-438. DOI: 10.1007/BF00744631 Scopus РИНЦ OpenAlex

Плясова Л.М. , Ищенко С.А. , Мамаева Е.К. , Рухадзе Е.Г. , Кейер Н.П. , Быстренко Т.Н.
Синтез и рентгеноструктурное исследование α-тиопиколинанилидатов меди и никеля
Журнал структурной химии. 1971. Т.12. №3. С.474-477. WOS РИНЦ ANCAN

Submitted:	Apr 12, 1969
Published print:	May 1, 1971

Scopus:	2-s2.0-34250462021
Elibrary:	28936300
OpenAlex:	W2093436999

Пока нет цитирований