Effect of Ligand Exchange on the EPR Spectra of the Cupric Diethyldithiocarbamate Complex | Sciact - CRIS-system of Boreskov Institute of Catalysis

Effect of Ligand Exchange on the EPR Spectra of the Cupric Diethyldithiocarbamate Complex Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 1971, Volume: 12, Number: 4, Pages: 548-554 Pages count : 7 DOI: 10.1007/BF00743665

Tags

Physical Chemistry; Inorganic Chemistry; Ligand Exchange; Diethyldithiocarbamate; Diethyldithiocarbamate Complex

Authors

Shklyaev A.A. ¹ , Anufrienko V.F. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

The effect of the interaction between the Cu(DTC) 2 complex and pyridine on the behavior of the EPR spectra in solution was investigated. It was shown that the anomalous nature of the spectra in the mixed solvent is due to rapid exchange between the various coordination states of the complex. By the analysis of the exchange spectra using solutions of the Bloch equations modified for the case of chemical exchange it was possible to determine the equilibrium constants and to evaluate the rate constants for the equilibrium reaction involved in the formation of the pentacoordinated adduct and its dissociation. The energy parameters of the reaction were determined from the temperature dependence of the constants

Shklyaev A.A. , Anufrienko V.F.
Effect of Ligand Exchange on the EPR Spectra of the Cupric Diethyldithiocarbamate Complex
Journal of Structural Chemistry. 1971. V.12. N4. P.548-554. DOI: 10.1007/BF00743665 Scopus РИНЦ OpenAlex

Шкляев А.А. , Ануфриенко В.Ф.
Влияние обмена лигандами на спектры ЭПР комплекса диэтилдитиокарбамата Cu(II)
Журнал структурной химии. 1971. Т.12. №4. С.601-608. WOS РИНЦ ANCAN

Submitted:	Jan 30, 1970
Published print:	Jul 1, 1971

Scopus:	2-s2.0-34250474059
Elibrary:	30657015
OpenAlex:	W2001092948

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