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Vanadium-Containing Nickel Phosphate Molecular Sieves as Catalysts for alfa-Pinene Oxidation with Molecular Oxygen: A Study of the Effect of Vanadium Content on Activity and Selectivity Научная публикация

Журнал Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169
Вых. Данные Год: 2012, Том: 363-364, Страницы: 328-334 Страниц : 7 DOI: 10.1016/j.molcata.2012.07.008
Ключевые слова α-Pinene, Nickel phosphate molecular sieve, Oxidation, Oxygen, Vanadium, VSB-5
Авторы Timofeeva M.N. 1,2 , Hasan Zubair 3 , Panchenko V.N. 1 , Prosvirin I.P. 1 , Jhung Sung Hwa 3
Организации
1 Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
2 Novosibirsk State Technichal University, Prospekt K. Marksa 20, 630092 Novosibirsk, Russian Federation
3 Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Sankyuck-Dong, Buk-Ku, Daegu 702-701, Republic of Korea

Информация о финансировании (1)

1 Kyungpook National University

Реферат: Vanadium-containing nickel phosphate molecular sieves (V-VSB-5) were applied as heterogeneous catalysts for the liquid phase oxidation of α-pinene with molecular oxygen at 60 °C. It has been found that the vanadium content in V-VSB-5 materials affects the conversion of α-pinene and product distribution. The conversion of α-pinene increases with increasing of V content. The major products were α-pinene oxide, verbenol and verbenone. Acid–base properties of V-VSB-5 affect the distribution of by-products formed via the isomerization of α-pinene oxide over Lewis acid sites and Brönsted acid sites to campholenic aldehyde and trans-carveol. The increase in V content in V-VSB-5 leads to the increase in isomerization of α-pinene oxide to trans-carveol and decrease in that to campholenic aldehyde
Библиографическая ссылка: Timofeeva M.N. , Hasan Z. , Panchenko V.N. , Prosvirin I.P. , Jhung S.H.
Vanadium-Containing Nickel Phosphate Molecular Sieves as Catalysts for alfa-Pinene Oxidation with Molecular Oxygen: A Study of the Effect of Vanadium Content on Activity and Selectivity
Journal of Molecular Catalysis A: Chemical. 2012. V.363-364. P.328-334. DOI: 10.1016/j.molcata.2012.07.008 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 7 мая 2012 г.
Принята к публикации: 8 июл. 2012 г.
Опубликована online: 17 июл. 2012 г.
Опубликована в печати: 1 нояб. 2012 г.
Идентификаторы БД:
Web of science: WOS:000309443400043
Scopus: 2-s2.0-84866037494
РИНЦ: 20480441
Chemical Abstracts: 2012:1332189
Chemical Abstracts (print): 157:551184
OpenAlex: W2029976104
Цитирование в БД:
БД Цитирований
Web of science 16
Scopus 17
РИНЦ 16
OpenAlex 19
Альметрики: