Structure of Zirconia Nanoparticles used for Pillaring of Clay Научная публикация
| Конференция |
2001 MRS Fall Meeting 25-30 нояб. 2001 , Boston |
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| Сборник | Nanophase and nanocomposite materials IV : symposium held November 26-29, 2001, Boston, Massachusetts, U.S.A. (Materials Research Society symposium proceedings, Vol. 703) Сборник, Materials Research Society. Warrendale, Pennsylvania.2002. 607 c. ISBN 1558996397. |
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| Журнал |
MRS Online Proceedings Library
ISSN: 1946-4274 |
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| Вых. Данные | Год: 2001, Том: 703, Номер статьи : 1321, Страниц : 6 DOI: 10.1557/PROC-703-V13.21 | ||||||
| Ключевые слова | Adsorption isotherms; Clay; Fourier transform infrared spectroscopy; Ultraviolet spectroscopy; X ray analysis; X ray scattering; Zirconia | ||||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 97-11720 |
Реферат:
SAXS and EXAFS were applied to study genesis of polynuclear zirconium hydroxyspecies in pillaring solutions as dependent upon the zirconium concentration, addition of alkaline-earth chlorides and aging. After the montmorillonite clay pillaring, the structure of zirconium nanopillars was characterized by applying X-ray structural analysis, UV-Vis, FTIRS of adsorbed CO and nitrogen adsorption isotherms. Main pillaring species appear to be nanorods comprised of several Zr4 tetramers. Basic structural features of the tetramers are preserved in zirconia nanoparticles fixed between alumosilicate layers in pillared clays. In calcined samples, those nanoparticles contain only bridging hydroxyls and/or oxygen anions responsible for bonding within pillars and between pillars and clay sheets.
Библиографическая ссылка:
Sadykov V.A.
, Kuznetsova T.G.
, Doronin V.P.
, Sorokina T.P.
, Kochubey D.I.
, Novgorodov B.N.
, Kolomijchuk V.N.
, Moroz E.M.
, Zyuzin D.A.
, Paukshtis E.A.
, Fenelonov V.B.
, Derevyankin A.Y.
, Beloshapkin S.A.
, Matyshak V.A.
, Konin G.A.
, Ross J.R.
Structure of Zirconia Nanoparticles used for Pillaring of Clay
В сборнике Nanophase and nanocomposite materials IV : symposium held November 26-29, 2001, Boston, Massachusetts, U.S.A. (Materials Research Society symposium proceedings, Vol. 703). – Materials Research Society., 2001. – C.529-534. – ISBN 1558996397. DOI: 10.1557/PROC-703-V13.21 WOS Scopus РИНЦ CAPlusCA OpenAlex
Structure of Zirconia Nanoparticles used for Pillaring of Clay
В сборнике Nanophase and nanocomposite materials IV : symposium held November 26-29, 2001, Boston, Massachusetts, U.S.A. (Materials Research Society symposium proceedings, Vol. 703). – Materials Research Society., 2001. – C.529-534. – ISBN 1558996397. DOI: 10.1557/PROC-703-V13.21 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована в печати: | 1 янв. 2001 г. |
| Опубликована online: | 15 мар. 2011 г. |
Идентификаторы БД:
| Web of science: | WOS:000177252100079 |
| Scopus: | 2-s2.0-0036353331 |
| РИНЦ: | 15032384 |
| Chemical Abstracts: | 2002:501808 |
| Chemical Abstracts (print): | 137:225652 |
| OpenAlex: | W2164595735 |