Spectroscopic Investigation of Structure and Mechanism of Proton Conductivity CsHSO4 and Composites CsHSO4 /SiO2 Full article
| Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2005, Volume: 46, Number: 4, Pages: 608-618 Pages count : 11 DOI: 10.1007/s10947-006-0178-y | ||||
| Tags | Composites, CsHSO 4, Disordered phases, Hydrogen bond, IR and RS spectra, Proton electrolytes | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 02-03-33332 |
| 2 | Russian Foundation for Basic Research | 03-03-39006 |
Abstract:
IR and RS spectra, structural, thermodynamical and transport properties of CsHSO4 and CsHSO4/SiO2 composites have been investigated. It is shown that CsHSO4 is stabilized in composites in phase II (monoclinic modification), which turns into amorphous state with increasing silicon dioxide content. A formation of disordered highly conducting states of CsHSO4 in composites at the temperatures noticeably lower than superionic phase transition was stated. Bond length equalization in sulfate-ions, weakening of hydrogen bond system, and as a result easier proton transfer in composites in comparison with pure salt take place in these conducting states. Mechanism for formation of composites and their proton conductivity is proposed.
Cite:
Burgina E.B.
, Ponomareva V.G.
, Baltakhinov V.P.
, Kostrovskiy V.G.
Spectroscopic Investigation of Structure and Mechanism of Proton Conductivity CsHSO4 and Composites CsHSO4 /SiO2
Journal of Structural Chemistry. 2005. V.46. N4. P.608-618. DOI: 10.1007/s10947-006-0178-y WOS Scopus РИНЦ ANCAN OpenAlex
Spectroscopic Investigation of Structure and Mechanism of Proton Conductivity CsHSO4 and Composites CsHSO4 /SiO2
Journal of Structural Chemistry. 2005. V.46. N4. P.608-618. DOI: 10.1007/s10947-006-0178-y WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Бургина Е.Б.
, Пономарева В.Г.
, Балтахинов В.П.
, Костровский В.Г.
Спектроскопическое исследование строения и механизма протонной проводимости CsHSO4 и композитов CsHSO4/SiO2
Журнал структурной химии. 2005. Т.46. №4. С.630-640. РИНЦ
Спектроскопическое исследование строения и механизма протонной проводимости CsHSO4 и композитов CsHSO4/SiO2
Журнал структурной химии. 2005. Т.46. №4. С.630-640. РИНЦ
Dates:
| Submitted: | Oct 14, 2004 |
| Published print: | Jul 1, 2005 |
Identifiers:
| Web of science: | WOS:000240067000005 |
| Scopus: | 2-s2.0-33746796820 |
| Elibrary: | 13502647 |
| Chemical Abstracts: | 2006:938458 |
| Chemical Abstracts (print): | 146:152639 |
| OpenAlex: | W2016497583 |