Structure of Zirconium Butoxide Complexes in n -Butanol Solutions Full article
| Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2006, Volume: 47, Number: 3, Pages: 453-457 Pages count : 5 DOI: 10.1007/s10947-006-0322-8 | ||||
| Tags | EXAFS, Organic solutions of zirconium, Zirconium butoxide | ||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 05-03- 32326 |
| 2 | Civilian Research and Development Foundation | 00-0863 |
| 3 | Civilian Research and Development Foundation | NO-008-X1 |
Abstract:
EXAFS and SAXS were used for structure elucidation of zirconium butoxide complexes in n-butanol at concentrations from 0.3 g to 0.015 g ZrO2 in 1 ml. The basic structural unit of the complex is a tetramer. It has two equal sides with zirconium atoms linked by double oxygen bridges and with zirconium-zirconium distances of 3.5 Å. The other sides in the tetramer are 3.3 Å and 3.9 Å. This difference in bond lengths is explained by the different numbers of double or single ligand bridges between zirconium atoms. The tetramers are apt to undergo oligomerization to form particles with a diameter of 80 Å in solution.
Cite:
Kanazhevskii V.V.
, Shmachkova V.P.
, Kotsarenko N.S.
, Kolomiichuk V.N.
, Kochubey D.I.
Structure of Zirconium Butoxide Complexes in n -Butanol Solutions
Journal of Structural Chemistry. 2006. V.47. N3. P.453-457. DOI: 10.1007/s10947-006-0322-8 WOS Scopus РИНЦ ANCAN OpenAlex
Structure of Zirconium Butoxide Complexes in n -Butanol Solutions
Journal of Structural Chemistry. 2006. V.47. N3. P.453-457. DOI: 10.1007/s10947-006-0322-8 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Канажевский В.В.
, Шмачкова В.П.
, Коцаренко Н.С.
, Коломийчук В.Н.
, Кочубей Д.И.
Строение комплексов бутоксида циркония в растворах н-бутанола
Журнал структурной химии. 2006. Т.47. №3. С.468-472. RSCI РИНЦ
Строение комплексов бутоксида циркония в растворах н-бутанола
Журнал структурной химии. 2006. Т.47. №3. С.468-472. RSCI РИНЦ
Dates:
| Submitted: | May 27, 2005 |
| Published print: | May 1, 2006 |
Identifiers:
| Web of science: | WOS:000242330700009 |
| Scopus: | 2-s2.0-33750705623 |
| Elibrary: | 13525866 |
| Chemical Abstracts: | 2006:1163999 |
| Chemical Abstracts (print): | 147:267662 |
| OpenAlex: | W2082356968 |