Mechanism of Iso-Butane Alkylation by Butenes over H3PW12O40, H3PTiW11O39, and Zr Supported Catalysts Full article
| Conference |
12th International Congress on Catalysis 09-14 Jul 2000 , Granada |
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| Source | 12th International Congress on Catalysis : Proceedings of the 12th ICC
9-14 July 2000, Granada, Spain Compilation, 2000. 3940 c. ISBN 9780444504807. |
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| Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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| Output data | Year: 2000, Volume: 130, Number: Part C, Article number : P268, Pages count : 6 DOI: 10.1016/S0167-2991(00)80852-6 | ||
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Abstract:
In the present paper we report on the mechanism of i-butane alkylation by butenes using three types of well defined catalysts. The first type catalysts are composed heteropolyacids supported on a carbon support. The second type catalysts are represented by sulfated zirconia supported on silica. The third type catalysts were prepared with molecular design using alkyl zirconium complexes. Zirconium cations in coordinatively unsaturated state are shown to be responsible for alkylation. Reaction mechanism is suggested, involving carbenium ions and zirconium hydrides generation from i-butane.
Cite:
Paukshtis E.A.
, Duplyakin V.K.
, Finevich V.P.
, Lavrenov A.V.
, Kirillov V.L.
, Kuznetsova L.I.
, Likholobov V.A.
, Balʹzhinimaev B.S.
Mechanism of Iso-Butane Alkylation by Butenes over H3PW12O40, H3PTiW11O39, and Zr Supported Catalysts
In compilation 12th International Congress on Catalysis : Proceedings of the 12th ICC 9-14 July 2000, Granada, Spain. 2000. – C.2543-2548. – ISBN 9780444504807. DOI: 10.1016/S0167-2991(00)80852-6 Scopus РИНЦ ANCAN OpenAlex
Mechanism of Iso-Butane Alkylation by Butenes over H3PW12O40, H3PTiW11O39, and Zr Supported Catalysts
In compilation 12th International Congress on Catalysis : Proceedings of the 12th ICC 9-14 July 2000, Granada, Spain. 2000. – C.2543-2548. – ISBN 9780444504807. DOI: 10.1016/S0167-2991(00)80852-6 Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published print: | Jan 1, 2000 |
| Published online: | Sep 2, 2007 |
Identifiers:
| Scopus: | 2-s2.0-0034350771 |
| Elibrary: | 13358368 |
| Chemical Abstracts: | 2000:566821 |
| Chemical Abstracts (print): | 133:254626 |
| OpenAlex: | W2086999634 |