Linalool Synthesis from α-Pinene: Kinetic Peculiarities of Catalytic Steps Научная публикация
| Журнал |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Вых. Данные | Год: 2001, Том: 211, Номер: 1, Страницы: 91-107 Страниц : 17 DOI: 10.1016/S0926-860X(00)00841-3 | ||
| Ключевые слова | Aromatic compounds; Catalyst selectivity; Hydrogenation; Isomerization; Oxidation; Reaction kinetics; Synthesis (chemical) | ||
| Авторы |
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| Организации |
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Реферат:
Synthesis of linalool from α-pinene which includes consecutively α-pinene hydrogenation to pinane on Pd/C catalyst, pinane oxidation to pinane-hydroperoxide by molecular oxygen and pinane-hydroperoxide hydrogenation to pinanol on Pd/C catalyst followed by its thermal isomerization to linalool is discussed. The effects of the reagent concentrations, temperature and catalyst content on the reaction rate and selectivity are studied. The kinetic peculiarities and the mechanisms of reactions are presented. The synthetic conditions of high-selective linalool preparation are found.
Библиографическая ссылка:
Semikolenov V.A.
, Ilʹina I.I.
, Simakova I.L.
Linalool Synthesis from α-Pinene: Kinetic Peculiarities of Catalytic Steps
Applied Catalysis A: General. 2001. V.211. N1. P.91-107. DOI: 10.1016/S0926-860X(00)00841-3 WOS Scopus РИНЦ OpenAlex CAPlusCA
Linalool Synthesis from α-Pinene: Kinetic Peculiarities of Catalytic Steps
Applied Catalysis A: General. 2001. V.211. N1. P.91-107. DOI: 10.1016/S0926-860X(00)00841-3 WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Поступила в редакцию: | 21 мар. 2000 г. |
| Принята к публикации: | 31 окт. 2000 г. |
| Опубликована online: | 7 мар. 2001 г. |
| Опубликована в печати: | 16 мар. 2001 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000167626600009 |
| ≡ Scopus: | 2-s2.0-0035278461 |
| ≡ РИНЦ: | 13374066 |
| ≡ OpenAlex: | W2061399244 |
| ≡ Chemical Abstracts: | 2001:177560 |
| ≡ Chemical Abstracts (print): | 135:5711 |