Effect of Portionwise Addition of Oxidant in Asymmetric Vanadium-Catalyzed Sulfide Oxidation Full article
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Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Output data | Year: 2000, Volume: 157, Number: 1-2, Pages: 91-95 Pages count : 5 DOI: 10.1016/S1381-1169(00)00037-6 | ||
| Tags | Asymmetric oxidation, Chiral Shift bases, Sulfides, Sulfoxides, V(IV)-complexes | ||
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Abstract:
Portionwise addition of hydrogen peroxide markedly augments enantioselectivity of sulfide to sulfoxide oxidation catalyzed by vanadium (IV)-Shiff base complexes, and this effect cannot be explained by temperature fluctuations. 51V NMR spectra of reaction mixture detect two chiral peroxo complexes and one achiral diperoxo compound.
Cite:
Karpyshev N.N.
, Yakovleva O.D.
, Talsi E.P.
, Bryliakov K.P.
, Tolstikova O.V.
, Tolstikov A.G.
Effect of Portionwise Addition of Oxidant in Asymmetric Vanadium-Catalyzed Sulfide Oxidation
Journal of Molecular Catalysis A: Chemical. 2000. V.157. N1-2. P.91-95. DOI: 10.1016/S1381-1169(00)00037-6 WOS Scopus РИНЦ ANCAN OpenAlex
Effect of Portionwise Addition of Oxidant in Asymmetric Vanadium-Catalyzed Sulfide Oxidation
Journal of Molecular Catalysis A: Chemical. 2000. V.157. N1-2. P.91-95. DOI: 10.1016/S1381-1169(00)00037-6 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jul 25, 1999 |
| Accepted: | Dec 24, 1999 |
| Published online: | Jun 19, 2000 |
| Published print: | Jun 20, 2000 |
Identifiers:
| Web of science: | WOS:000087952600012 |
| Scopus: | 2-s2.0-0034691157 |
| Elibrary: | 13354859 |
| Chemical Abstracts: | 2000:413455 |
| Chemical Abstracts (print): | 133:237418 |
| OpenAlex: | W2082503673 |