Preparation and Catalytic Study of Metal Modified TS-1 in the Oxidation of Benzene to Phenol by N2O Full article
| Journal |
Microporous and Mesoporous Materials
ISSN: 1387-1811 , E-ISSN: 1873-3093 |
||||
|---|---|---|---|---|---|
| Output data | Year: 2001, Volume: 48, Number: 1-3, Pages: 345-353 Pages count : 9 DOI: 10.1016/S1387-1811(01)00351-1 | ||||
| Tags | α-sites, Benzene to phenol oxidation, Fe-TS-1, Metal modified TS-1, Nitrous oxide, TS-1 | ||||
| Authors |
|
||||
| Affiliations |
|
Abstract:
The titanosilicalite TS-1 samples modified by Al, V, Cr, Fe, Co and Ru were synthesized, characterized and tested in the title reaction. As with the earlier studied zeolite systems, Fe introduction into the TS-1 matrix produces α-sites that can catalyze the oxidation of benzene to phenol with high activity and selectivity. Other metals are shown to be inert. The quantitative dependencies of the catalytic activity on Fe content and on α-site concentration are discussed.
Cite:
Pirutko L.V.
, Uriarte A.
, Chernyavsky V.S.
, Kharitonov A.S.
, Panov G.I.
Preparation and Catalytic Study of Metal Modified TS-1 in the Oxidation of Benzene to Phenol by N2O
Microporous and Mesoporous Materials. 2001. V.48. N1-3. P.345-353. DOI: 10.1016/S1387-1811(01)00351-1 WOS Scopus РИНЦ OpenAlex ANCAN
Preparation and Catalytic Study of Metal Modified TS-1 in the Oxidation of Benzene to Phenol by N2O
Microporous and Mesoporous Materials. 2001. V.48. N1-3. P.345-353. DOI: 10.1016/S1387-1811(01)00351-1 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Aug 6, 2000 |
| Accepted: | Feb 12, 2001 |
| Published online: | Oct 16, 2001 |
| Published print: | Nov 1, 2001 |
Identifiers:
| ≡ Web of science: | WOS:000171908700043 |
| ≡ Scopus: | 2-s2.0-0035504137 |
| ≡ Elibrary: | 13366962 |
| ≡ OpenAlex: | W2059933145 |
| ≡ Chemical Abstracts: | 2001:780138 |
| ≡ Chemical Abstracts (print): | 136:87460 |