Recent Advances in Transition-Metal-Catalyzed Selective Oxidation of Substituted Phenols and Methoxyarenes with Environmentally Benign Oxidants Review
| Journal |
Coordination Chemistry Reviews
ISSN: 0010-8545 , E-ISSN: 1873-3840 |
||||
|---|---|---|---|---|---|
| Output data | Year: 2016, Volume: 306, Number: Part 1, Pages: 302-330 Pages count : 29 DOI: 10.1016/j.ccr.2015.07.019 | ||||
| Tags | Catalysis, Environmentally benign oxidants, Methoxyarenes, Phenols, Quinones, Selective oxidation | ||||
| Authors |
|
||||
| Affiliations |
|
Funding (2)
| 1 | Russian Foundation for Basic Research | 14-03-31431 |
| 2 | Russian Foundation for Basic Research | 13-03-12042 |
Abstract:
The selective catalytic oxidation of organic compounds with atom-efficient, cheap and readily available oxidants is widely recognized as the most economic and ecological route to many valuable oxygen-containing products and intermediates of organic synthesis. In the last two decades, a considerable scientific effort was directed to the development of catalytic systems that employ environmentally benign oxidants to convert aromatic compounds to oxygenated products, which serve as versatile building blocks in the synthesis of vital biologically active compounds. The present review summarizes recent advances in transition-metal-catalyzed liquid-phase selective oxidation of substituted phenols and methoxyarenes with molecular oxygen, hydrogen peroxide, and t-butyl hydroperoxide, covering both homogeneous and heterogeneous catalysts. The review highlights the scope and limitations of the existing methods and discusses mechanistic features of these important catalytic oxidation reactions. For solid catalysts, special attention is paid to analysis of the critical issues of the nature of catalysis, metal leaching under conditions of liquid phase oxidation reactions, and catalyst reusability.
Cite:
Kholdeeva O.A.
, Zalomaeva O.V.
Recent Advances in Transition-Metal-Catalyzed Selective Oxidation of Substituted Phenols and Methoxyarenes with Environmentally Benign Oxidants
Coordination Chemistry Reviews. 2016. V.306. NPart 1. P.302-330. DOI: 10.1016/j.ccr.2015.07.019 WOS Scopus РИНЦ ANCAN OpenAlex
Recent Advances in Transition-Metal-Catalyzed Selective Oxidation of Substituted Phenols and Methoxyarenes with Environmentally Benign Oxidants
Coordination Chemistry Reviews. 2016. V.306. NPart 1. P.302-330. DOI: 10.1016/j.ccr.2015.07.019 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Mar 17, 2015 |
| Accepted: | Jul 31, 2015 |
| Published online: | Aug 8, 2015 |
| Published print: | Jan 1, 2016 |
Identifiers:
| Web of science: | WOS:000367483100011 |
| Scopus: | 2-s2.0-84939865525 |
| Elibrary: | 24934003 |
| Chemical Abstracts: | 2015:1342882 |
| Chemical Abstracts (print): | 170:209128 |
| OpenAlex: | W1474093089 |