Catalysts for Non-Oxidative Methane Conversion Full article
| Conference |
9th International Symposium on the Scientific Bases for the Preparation of Heterogeneous Catalysts 10-14 Sep 2006 , Louvain-la-Neuve |
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| Source | Scientific Bases for the Preparation of Heterogeneous Catalysts Compilation, 2006. 1048 c. |
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| Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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| Output data | Year: 2006, Volume: 162, Pages: 913-920 Pages count : 8 DOI: 10.1016/S0167-2991(06)80997-3 | ||||
| Tags | clusters, high-silica zeolite, Keywords:synthesis, mesoporous, nanopowder | ||||
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Abstract:
A high-siliea ZSM-5 zeolite (SiO2/Al2O3=40) was synthesized and used to produce Mo-containing catalysts by different methods. Using the methods of high-resolution electron microscopy, energy dispersive X-ray spectrometry and thermoprogrammed ammonia desorption the composition and acidic properties of Mo-ZSM-5 catalysts were studied. The catalytic tests of the samples were carried out in the process of non-oxidative methane conversion at 750°C. It has been shown that two forms of molybdenum-containing particles are stabilized during the reaction: molybdenum carbide particles (of size 2-10 nm) located on the zeolite surface, and clusters (of size less than 1 nm) located inside its channels. It has been established that the clusters of oxidized molybdenum are the main sites of methane activation localized in open molecular pores of a zeolite
Cite:
Vosmerikov A.V.
, Zaikovskii V.I.
, Korobitsyna L.L.
, Kodenev E.G.
, Kozlov V.V.
, Echevsky G.V.
Catalysts for Non-Oxidative Methane Conversion
In compilation Scientific Bases for the Preparation of Heterogeneous Catalysts. 2006. – C.913-920. DOI: 10.1016/S0167-2991(06)80997-3 Scopus РИНЦ ANCAN OpenAlex
Catalysts for Non-Oxidative Methane Conversion
In compilation Scientific Bases for the Preparation of Heterogeneous Catalysts. 2006. – C.913-920. DOI: 10.1016/S0167-2991(06)80997-3 Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published print: | Jan 1, 2006 |
| Published online: | Sep 2, 2007 |
Identifiers:
| Scopus: | 2-s2.0-35248861542 |
| Elibrary: | 13524539 |
| Chemical Abstracts: | 2008:289075 |
| Chemical Abstracts (print): | 151:35587 |
| OpenAlex: | W1542192994 |